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双(二叔丁基苯基膦)二氯化钯(II)

双(二叔丁基苯基膦)二氯化钯(II)名称

[ CAS 号 ]:
34409-44-4

[ 中文名 ]:
双(二叔丁基苯基膦)二氯化钯(II)

[ 英文名 ]:
Dichlorobis(di-|tert|-butylphenylphosphine)palladium(II)

[英文别名 ]:

PdCl2[P(t-Bu)2Ph]2
dichlorobis(phenyldi-tert-butylphosphine)palladium

双(二叔丁基苯基膦)二氯化钯(II)物理化学性质

[ 分子式 ]:
C₂₈H₄₆Cl₂P₂Pd

[ 分子量 ]:
621.938

[ 精确质量 ]:
620.148682

[ PSA ]:
27.18000

[ LogP ]:
10.16060

[ 外观性状 ]:
浅黄色到深黄色粉末

[ 储存条件 ]:
2~8°C

双(二叔丁基苯基膦)二氯化钯(II)MSDS

双(二叔丁基苯基膦)二氯化钯(II)安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 危害码 (欧洲) ]:
Xn

[ 安全声明 (欧洲) ]:
36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

双(二叔丁基苯基膦)二氯化钯(II)合成路线

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双(二叔丁基苯基膦)二氯化钯(II)文献

New air-stable catalysts for general and efficient suzuki-miyaura cross-coupling reactions of heteroaryl chlorides.

Org. Lett. 8 , 1787, (2006)

[reaction: see text] New air-stable PdCl(2){P(t)Bu(2)(p-R-Ph)}(2) (R = H, NMe(2), CF(3),) complexes represent simple, general, and efficient catalysts for the Suzuki-Miyaura cross-coupling reactions o...

New catalysts for Suzuki-Miyaura coupling reactions of heteroatom-substituted heteroaryl chlorides.

J. Org. Chem. 72 , 5104, (2007)

The new air-stable PdCl2[PR2(Ph-R')]2 complexes, readily prepared from commercial reagents, exhibit unique efficiency as catalysts for the Suzuki-Miyaura coupling reactions of a variety of heteroatom-...

Palladium(0)-catalyzed cross-coupling of potassium (Z)-2-chloroalk-1-enyl trifluoroborates: a chemo- and stereoselective access to (Z)-chloroolefins and trisubstituted alkenes.

Chemistry 15 , 5793, (2009)

We describe the preparation of a series of new potassium trifluoroborates 1 and the study of their behaviour in a Pd(0)-catalyzed cross-coupling reaction. We found that compounds 1 are endowed with or...

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