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氯甲磺酰氯

氯甲磺酰氯用途

是有机合成中高效的离去基团，应用实例如下图所示：

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氯甲磺酰氯名称

[ CAS 号 ]:
3518-65-8

[ 中文名 ]:
氯甲磺酰氯

[ 英文名 ]:
Chloromesyl chloride

[中文别名 ]:

[英文别名 ]:

Chloromethanesulfonyl chloride
chloromethanesulphonyl chloride
Chloromethylsulphonyl chloride
monochloromethylsulfonyl chloride
Chloromesyl chloride
Methanesulfonyl chloride,chloro
monochloromethanesulfonyl chloride
chloromethyl sulphonyl chloride
MFCD00014727
EINECS 222-526-1

氯甲磺酰氯物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
197.8±23.0 °C at 760 mmHg

[ 分子式 ]:
CH₂Cl₂O₂S

[ 分子量 ]:
148.996

[ 闪点 ]:
73.4±22.6 °C

[ 精确质量 ]:
147.915253

[ PSA ]:
42.52000

[ LogP ]:
0.47

[ 外观性状 ]:
液体;Light yellow to Yellow to Orange clear liquid

[ 蒸汽压 ]:
0.5±0.4 mmHg at 25°C

[ 折射率 ]:
1.478

[ 储存条件 ]:
库房低温,通风,干燥,防火,与氧化剂,食品原料分开存放

氯甲磺酰氯MSDS

详细MSDS(安全技术说明书)

氯甲磺酰氯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: PB2800000

CHEMICAL NAME :: Methanesulfonyl chloride, chloro-

CAS REGISTRY NUMBER :: 3518-65-8

BEILSTEIN REFERENCE NO. :: 1811761

LAST UPDATED :: 199712

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C-H2-Cl2-O2-S

MOLECULAR WEIGHT :: 148.99

WISWESSER LINE NOTATION :: WSG1G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1070,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1070,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 372 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1070,1986

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氯甲磺酰氯安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R22;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
PB2800000

[ 包装等级 ]:
I

[ 危险类别 ]:
8

[ 海关编码 ]:
2904909090

氯甲磺酰氯上下游产品

氯甲磺酰氯上游产品

氯甲磺酰氯下游产品

氯甲磺酰氯海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%