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氨基甲酸9-芴基甲酯

氨基甲酸9-芴基甲酯用途

9-芴基甲氨基甲酸酯用作荧光团试剂,用于聚糖的荧光检测[1]。

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氨基甲酸9-芴基甲酯名称

[ CAS 号 ]:
35661-51-9

[ 中文名 ]:
9-芴基甲基肼基甲酸酯

[ 英文名 ]:
9-Fluorenylmethyl carbazate

[中文别名 ]:

[英文别名 ]:

Fmoc-hydrazide
Fmoc-hydrazine
(9H-Fluoren-9-yl)methyl hydrazinecarboxylate
Fmoc-NHNH2
9-Fluorenylmethyl Carbazate
[(9H-Fluoren-9-ylmethoxy)carbonyl]hydrazine
Carbazic Acid 9-Fluorenylmethyl Ester
9H-Fluoren-9-ylmethyl hydrazinecarboxylate
N-[(9H-fluoren-9-ylmethoxy)-carbonyl]-hydrazine
9-Fluorenylmethylcarbazate

氨基甲酸9-芴基甲酯生物活性

[ 描述 ]:

9-芴基甲氨基甲酸酯用作荧光团试剂,用于聚糖的荧光检测[1]。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Kinoshita M, et al. A practical method for preparing fluorescent-labeled glycans with a 9-fluorenylmethyl derivative to simplify a fluorimetric HPLC-based analysis. J Pharm Biomed Anal. 2020 Jul 15;186:113267.

氨基甲酸9-芴基甲酯物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
485.8±14.0 °C at 760 mmHg

[ 熔点 ]:
-170ºC (dec.)

[ 分子式 ]:
C₁₅H₁₄N₂O₂

[ 分子量 ]:
254.284

[ 闪点 ]:
247.6±20.1 °C

[ 精确质量 ]:
254.105530

[ PSA ]:
64.35000

[ LogP ]:
2.88

[ 外观性状 ]:
固体;White to Almost white powder to crystal

[ 蒸汽压 ]:
0.0±1.2 mmHg at 25°C

[ 折射率 ]:
1.632

[ 储存条件 ]:
2-8°C

氨基甲酸9-芴基甲酯MSDS

氨基甲酸9-芴基甲酯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-36

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2928000090

氨基甲酸9-芴基甲酯合成路线

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氨基甲酸9-芴基甲酯海关

[ 海关编码 ]: 2928000090

[ 中文概述 ]:
2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

氨基甲酸9-芴基甲酯文献

Synthesis and application of Fmoc-hydrazine for the quantitative determination of saccharides by reversed-phase high-performance liquid chromatography in the low and subpicomole range.

Anal. Biochem. 195 , 160, (1991)

A new derivatization reagent, Fmoc-hydrazine, has been synthesized from the reaction of Fmoc-chloroformate with hydrazine as a precolumn fluorometric labeling reagent for reducing sugars such as gluco...

Simple and sensitive multi-sugar-probe gut permeability test by high-performance liquid chromatography with fluorescence labelling.

J. Chromatogr. A. 730(1-2) , 99-105, (1996)

Enteral intake of a mixture of inert, non-metabolic monosaccharide and disaccharide probes, followed by measurement of their urinary probe ratio, is a well known method to investigate gut permeability...

A sensitive fluorescence reagent for the determination of aldehydes from alcoholic beverage using high-performance liquid chromatography with fluorescence detection and mass spectrometric identification.

Anal. Chim. Acta 636(1) , 95-104, (2009)

A pre-column derivatization method for the sensitive determination of aldehydes using the tagging reagent 2-[2-(7H-dibenzo[a,g] carbazol-7-yl)-ethoxy] ethyl carbonylhydrazine (DBCEEC) followed by high...

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