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3-苯氧基甲苯

3-苯氧基甲苯用途

【用途一】
用作农药除虫菊酯类中间体
【用途二】
间苯氧基甲苯是合成拟除虫菊酯的关键中间体，主要用以生产间苯氧基苯甲醛。
【用途三】
该品用作拟除虫菊酯杀虫剂、压敏染料、香料的中间体。

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3-苯氧基甲苯名称

[ CAS 号 ]:
3586-14-9

[ 中文名 ]:
3-苯氧基甲苯

[ 英文名 ]:
1-Methyl-3-phenoxybenzene

[中文别名 ]:

[英文别名 ]:

Phenyl m-tolyl ether
EINECS 222-716-4
3-Methyldiphenyl Ether
1-Methyl-3-phenoxybenzene
3-Phenoxytoluene
3-methyl diphenyl ether
Benzene, 1-methyl-3-phenoxy-
m-Methylphenyl phenyl ether
BENZENE,1-METHYL-3-PHENOXY
3-Methylphenyl phenyl ether

3-苯氧基甲苯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
269.1±9.0 °C at 760 mmHg

[ 分子式 ]:
C₁₃H₁₂O

[ 分子量 ]:
184.234

[ 闪点 ]:
110.8±14.4 °C

[ 精确质量 ]:
184.088821

[ PSA ]:
9.23000

[ LogP ]:
4.67

[ 外观性状 ]:
透明非常略黄色液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.566

[ 储存条件 ]:
室温，密封，干燥

3-苯氧基甲苯MSDS

3-苯氧基甲苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA6142000

CHEMICAL NAME :: Benzene, 1-methyl-3-phenoxy-

CAS REGISTRY NUMBER :: 3586-14-9

BEILSTEIN REFERENCE NO. :: 2045714

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C13-H12-O

MOLECULAR WEIGHT :: 184.25

WISWESSER LINE NOTATION :: 1R COR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2509 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - acute pulmonary edema

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 50 ug/plate

REFERENCE :: CHYCDW Zhonghua Yufangyixue Zazhi. Chinese Journal of Preventive Medicine. (China International Book Trading Corp., POB 2820, Beijing, Peop. Rep. China) Beginning history not known. Volume(issue)/page/year: 21,240,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3741 No. of Facilities: 36 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 145 (estimated) No. of Female Employees: 73 (estimated)

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3-苯氧基甲苯安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 安全声明 (欧洲) ]:
S23-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
DA6142000

[ 海关编码 ]:
2909309090

3-苯氧基甲苯合成路线

3-苯氧基甲苯制备

间甲酚与氢氧化钾溶液配制成酚钾后，与氯苯进行催化缩合，生成3-苯氧基甲苯。缩合产物经酸、碱处理，除去间甲酚钾、间甲酚等残留杂质，得到纯度≥98%的成品，以间甲酚计，收率约82%。

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3-苯氧基甲苯海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

3-苯氧基甲苯文献

Metabolism of 3-methyldiphenyl ether by Sphingomonas sp. SS31.

FEMS Microbiol. Lett. 75(2-3) , 253-8, (1992)

The bacterium Sphingomonas sp. SS31, which was obtained from the diphenyl ether-degrading strain Sphingomonas sp. SS3 by an adaptation process, utilized 3-methyldiphenyl ether for growth in addition t...

First steps towards a Zn/Co(III)sep-driven P450 BM3 reactor.

Appl. Microbiol. Biotechnol. 91(4) , 989-99, (2011)

Cytochrome P450s are synthetically attractive hydroxylation catalysts. For cell-free applications, a constant supply of NAD(P)H can be very costly. Mediators such as Zn/Co(III)sep can be an alternativ...

更多文献

3-苯氧基甲苯

3-苯氧基甲苯用途

3-苯氧基甲苯名称

3-苯氧基甲苯物理化学性质

3-苯氧基甲苯MSDS

详细MSDS(安全技术说明书)

3-苯氧基甲苯毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

3-苯氧基甲苯安全信息

3-苯氧基甲苯合成路线

详细合成路线

3-苯氧基甲苯制备

3-苯氧基甲苯海关

3-苯氧基甲苯文献

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