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1,1,1-三氟乙酰丙酮

1,1,1-三氟乙酰丙酮用途

溶剂。气相色谱分析分离铬和铑。萃取剂。螯合剂。无机离子的鉴定、分离和提纯。有机合成。

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1,1,1-三氟乙酰丙酮名称

[ CAS 号 ]:
367-57-7

[ 中文名 ]:
1,1,1-三氟-2,4-戊二酮

[ 英文名 ]:
1,1,1-Trifluoroacetylacetone

[中文别名 ]:

[英文别名 ]:

2,4-Pentanedione, 1,1,1-trifluoro-
FXFFV1V1
α,α,α-Trifluoroacetylacetone
1,1,1-Trifluoroacetylacetone
1,1,1-trifluoropentane-2,4-dione
MFCD00000427
(Trifluoroacetyl)acetone
1,1,1-Trifluoro-2,4-pentanedione
Trifluoroacetylacetone
Palladium(II)trifluoro-2,4-pentanedionate

1,1,1-三氟乙酰丙酮物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
106.0±0.0 °C at 760 mmHg

[ 分子式 ]:
C₅H₅F₃O₂

[ 分子量 ]:
154.087

[ 闪点 ]:
26.1±0.0 °C

[ 精确质量 ]:
154.024170

[ PSA ]:
34.14000

[ LogP ]:
2.09

[ 外观性状 ]:
深褐色-黄色

[ 蒸汽压 ]:
28.8±0.2 mmHg at 25°C

[ 折射率 ]:
1.343

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
slightly soluble

1,1,1-三氟乙酰丙酮MSDS

1,1,1-三氟乙酰丙酮安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H302 + H312 + H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R10;R20/21/22;R36/37/38

[ 安全声明 (欧洲) ]:
S36/37-S36/37/39-S26-S16

[ 危险品运输编码 ]:
UN 1224 3/PG 3

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
29147090

1,1,1-三氟乙酰丙酮合成路线

1,1,1-三氟乙酰丙酮上下游产品

1,1,1-三氟乙酰丙酮上游产品

1,1,1-三氟乙酰丙酮下游产品

1,1,1-三氟乙酰丙酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

1,1,1-三氟乙酰丙酮文献

Inhibition by diacylmethane derivatives of mutagenicity in Salmonella typhimurium and tRNA-binding of chemical carcinogens.

Mutat. Res. 262(3) , 189-93, (1991)

Effects of diacylmethanes on the mutagenicity of 2-naphthohydroxamic acid, methylnitrosourea, benzo[a]pyrene and aflatoxin B1 in S. typhimurium and the tRNA binding by benzo[a]pyrene and aflatoxin B1 ...

Inhibition by diacylmethane derivatives of mutagenicity and nucleic acid binding of 2-aminofluorene derivatives.

J. Natl. Cancer Inst. 81(22) , 1743-7, (1989)

The active methylene compounds acetylacetone, 1,1,1-trifluoroacetylacetone, benzoylacetone, dibenzoylmethane, and 1,3-indandione inhibited the mutagenicity of 2-nitrofluorene in Salmonella typhimurium...

Synthesis and anticancer activity evaluation of new 2-alkylcarbonyl and 2-benzoyl-3-trifluoromethyl-quinoxaline 1,4-di-N-oxide derivatives.

Bioorg. Med. Chem. 12(13) , 3711-21, (2004)

As a continuation of our research in quinoxaline 1,4-di-N-oxide and with the aim of obtaining new anticancer agents, which can improve the current chemotherapeutic treatments, new series of 2-alkylcar...

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