三(2,2,2-三氟乙烷基)亚磷酸盐

三(2,2,2-三氟乙基)亚磷酸酯通过与2-溴-N-甲氧基-N-甲基乙酰胺发生Arbuzov反应,可以合成N-甲氧基-N-甲基双(2,2,2-三氟乙基)膦酰胺。

[ 密度 ]:
1.487

[ 沸点 ]:
128.8±40.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₆F₉O₃P

[ 分子量 ]:
328.069

[ 闪点 ]:
31.7±27.3 °C

[ 精确质量 ]:
327.991089

[ PSA ]:
41.28000

[ LogP ]:
2.98

[ 外观性状 ]:
液体;Colorless to Light yellow clear liquid

[ 蒸汽压 ]:
12.7±0.2 mmHg at 25°C

[ 折射率 ]:
1.324

[ 储存条件 ]:
存放于惰性气体之中;避免空气,湿气 (分解)

详细MSDS(安全技术说明书)

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2920901900

详细合成路线

[ 海关编码 ]: 2920901900

[ 中文概述 ]:
2920901900 亚磷酸酯。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2920901900 VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

A new bis(2,2,2-trifluoroethyl)phosphonate for the synthesis of Z-unsaturated N-methoxy-N-methylamides.

J. Org. Chem. 67(15) , 5437-9, (2002)

The N-methoxy-N-methyl bis(2,2,2-trifluoroethyl)phosphonamide was easily obtained via the Arbuzov reaction with use of commercially available tris(2,2,2-trifluoroethyl)phosphite, 2-bromo-N-methoxy-N-m...

Towards a safe lithium-sulfur battery with a flame-inhibiting electrolyte and a sulfur-based composite cathode.

Angew. Chem. Int. Ed. Engl. 53(38) , 10099-104, (2014)

Of the various beyond-lithium-ion batteries, lithium-sulfur (Li-S) batteries were recently reported as possibly being the closest to market. However, its theoretically high energy density makes it pot...

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：三(2,2,2-三氟乙烷基)亚磷酸盐

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥2780.9/100g ￥79.9/1g ￥257.9/5g ￥需询单/1g

联系人：阿拉丁

产品详情：三（2,2,2-三氟乙基）亚磷酸酯

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