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六氟苯

六氟苯用途

用作麻醉剂，为各种有机物的优良溶剂，特别用作氢核磁共振谱或闪烁计数器用溶剂。

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六氟苯名称

[ CAS 号 ]:
392-56-3

[ 中文名 ]:
六氟苯

[ 英文名 ]:
Perfluorobenzene

[中文别名 ]:

全氟苯

[英文别名 ]:

Benzene, 1,2,3,4,5,6-hexafluoro-
Hexafluorobenzene
MFCD00000288
EINECS 206-876-2
C6F6
Perfluorobenzene

六氟苯物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
80.5±35.0 °C at 760 mmHg

[ 熔点 ]:
3.7-4.1 °C(lit.)

[ 分子式 ]:
C₆F₆

[ 分子量 ]:
186.055

[ 闪点 ]:
10.0±0.0 °C

[ 精确质量 ]:
185.990417

[ LogP ]:
2.42

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
94.5±0.1 mmHg at 25°C

[ 折射率 ]:
1.374

[ 储存条件 ]:
Flammables area

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents. May form complexes with transition metals which can explode when heated. Highly flammable.

[ 水溶解性 ]:
水溶性：不溶

六氟苯MSDS

六氟苯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DA3050000

CHEMICAL NAME :: Benzene, hexafluoro-

CAS REGISTRY NUMBER :: 392-56-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C6-F6

MOLECULAR WEIGHT :: 186.06

WISWESSER LINE NOTATION :: FR BF CF DF EF FF

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >25 gm/kg

TOXIC EFFECTS :: Behavioral - excitement Gastrointestinal - hypermotility, diarrhea Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571186

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 95 gm/m3/2H

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - respiratory depression Lungs, Thorax, or Respiration - other changes

REFERENCE :: IZSBAI Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Biologomeditsinskikh Nauk. (Novosibirsk, USSR) No.1-3, 1963-68. For publisher information, see ISBNBN. Volume(issue)/page/year: 3,91,1965

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 11800 ppm/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Behavioral - ataxia Lungs, Thorax, or Respiration - other changes

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571186 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84193 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 41 (estimated)

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六氟苯安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225

[ 警示性声明 ]:
P210

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable

[ 风险声明 (欧洲) ]:
R11;R36/37/38

[ 安全声明 (欧洲) ]:
S16-S33-S7/9

[ 危险品运输编码 ]:
UN 1993 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
DA3050000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
2903999090

六氟苯合成路线

六氟苯上下游产品

六氟苯上游产品

六氟苯下游产品

六氟苯制备

主要杂质为五氟代苯。可用发烟硫酸在室温处理4h，使杂质磺化，再经水洗，五氧化二磷干燥，分步结晶，可得纯度为99.95%±0.05%、熔点为(5.082±0.005)℃的精制品。

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六氟苯海关

[ 海关编码 ]: 2903999090

[ 中文概述 ]:
2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

六氟苯文献

Gas chromatography with parallel hard and soft ionization mass spectrometry.

Rapid Commun. Mass Spectrom. 29(1) , 91-9, (2014)

Mass spectrometric identification of compounds in chromatography can be obtained from molecular masses from soft ionization mass spectrometry techniques such as field ionization (FI) and fragmentation...

Oxidative dehalogenation of perhalogenated benzenes by cytochrome P450 compound I.

Biochemistry 46(20) , 5924-40, (2007)

Resolution of the identity PBE (RI-PBE) and B3LYP density functional theory calculations are used to understand the cytochrome P450-catalyzed, Compound I-mediated oxidation of perchlorobenzenes, perfl...

The pH-dependence of organofluorine binding domain preference in dissolved humic acid.

Chemosphere 90(2) , 270-5, (2013)

In this study we explore the relationship between solution pH and the distribution of the binding interactions at different domains of a dissolved humic acid (HA) for three xenobiotics: pentafluoroani...

更多文献

六氟苯

六氟苯用途

六氟苯名称

六氟苯物理化学性质

六氟苯MSDS

详细MSDS(安全技术说明书)

六氟苯毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

六氟苯安全信息

六氟苯合成路线

详细合成路线

六氟苯上下游产品

六氟苯上游产品

六氟苯下游产品

六氟苯制备

六氟苯海关

六氟苯文献

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