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2-异丁酰环己酮

2-异丁酰环己酮名称

[ CAS 号 ]:
39207-65-3

[ 中文名 ]:
2-异丁酰基环己酮

[ 英文名 ]:
2-Isobutyrylcyclohexanone

[中文别名 ]:

2-(2-甲基-1-氧代丙烷)环己酮

[英文别名 ]:

2-Isobutyrylcyclohexanone
Cyclohexanone, 2-(2-methyl-1-oxopropyl)-
MFCD00466185
2-(2-methylpropanoyl)cyclohexan-1-one

2-异丁酰环己酮物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
265.9±23.0 °C at 760 mmHg

[ 熔点 ]:
38°C

[ 分子式 ]:
C₁₀H₁₆O₂

[ 分子量 ]:
168.233

[ 闪点 ]:
98.4±19.6 °C

[ 精确质量 ]:
168.115036

[ PSA ]:
34.14000

[ LogP ]:
0.96

[ 外观性状 ]:
液体;Colorless to Light orange to Yellow clear liquid

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.464

[ 储存条件 ]:
室温，干燥

2-异丁酰环己酮MSDS

2-异丁酰环己酮安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H319

[ 警示性声明 ]:
P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
R22;R36

[ 安全声明 (欧洲) ]:
S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
2914299000

2-异丁酰环己酮合成路线

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2-异丁酰环己酮海关

[ 海关编码 ]: 2914299000

[ 中文概述 ]:
2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

2-异丁酰环己酮文献

An alternative to the classical α-arylation: the transfer of an intact 2-iodoaryl from ArI(O₂CCF₃)₂.

Angew. Chem. Int. Ed. Engl. 53(42) , 11298-301, (2014)

The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative ...

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