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苯嗪草酮

苯嗪草酮用途

Metamitron 是一种出苗前和出苗后的除草剂,用于控制甜菜中的阔叶杂草和草。

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苯嗪草酮名称

[ CAS 号 ]:
41394-05-2

[ 中文名 ]:
苯嗪草酮

[ 英文名 ]:
Metamiton

[中文别名 ]:

[英文别名 ]:

Herbrak
Metamiton
Metron Stefes
Metamitron [BSI:ISO]
Goltix
MFCD00055524
T6NN DNVJ C1 DZ FR
Methiamitron [Belgium]
METAMITRON
BAY DRW 1139

苯嗪草酮生物活性

[ 描述 ]:

Metamitron 是一种出苗前和出苗后的除草剂,用于控制甜菜中的阔叶杂草和草。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Shizong Wang, et al. Identification of Degradation Routes of Metamitron in Soil Microcosms Using 13 C-isotope Labeling. Environ Pollut. 2017 Jan;220(Pt B):927-935.

苯嗪草酮物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
335.8±25.0 °C at 760 mmHg

[ 熔点 ]:
167-170 °C(lit.)

[ 分子式 ]:
C₁₀H₁₀N₄O

[ 分子量 ]:
202.213

[ 闪点 ]:
156.9±23.2 °C

[ 精确质量 ]:
202.085464

[ PSA ]:
73.80000

[ LogP ]:
0.83

[ 外观性状 ]:
淡黄色晶体

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.672

[ 储存条件 ]:
库房通风低温干燥

[ 水溶解性 ]:
水溶性：实际上不溶；水溶解度：1.7 g/l 20 °C；微溶：甲苯

苯嗪草酮MSDS

苯嗪草酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XZ3015000

CHEMICAL NAME :: as-Triazin-5(4H)-one, 4-amino-3-methyl-6-phenyl-

CAS REGISTRY NUMBER :: 41394-05-2

BEILSTEIN REFERENCE NO. :: 0613129

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C10-H10-N4-O

MOLECULAR WEIGHT :: 202.24

WISWESSER LINE NOTATION :: T6NN DNVJ C1 DZ FR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1447 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >331 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1450 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: >1 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: 1930 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Mold - Neurospora crassa

DOSE/DURATION :: 1 mg/L

REFERENCE :: ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 7(Suppl 3),11,1985

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苯嗪草酮安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H400

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R22;R50

[ 安全声明 (欧洲) ]:
S61-S45-S36/37

[ 危险品运输编码 ]:
UN 3077 9/PG 3

[ WGK德国 ]:
2

[ RTECS号 ]:
XZ3015000

[ 危险类别 ]:
9.0

[ 海关编码 ]:
2933699014

苯嗪草酮合成路线

苯嗪草酮上下游产品

苯嗪草酮上游产品

苯嗪草酮下游产品

苯嗪草酮海关

[ 海关编码 ]: 2933699014

[ 中文概述 ]:
HS: 2933699014 丁嗪草酮,环嗪酮,嗪草酮等〔包括苯嗪草酮,乙嗪草酮〕增值税率:17.0% 退税率:9.0% 监管条件:S(进出口农药登记证明) 最低关税:6.5% 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2933699014 4-amino-6-(tert-butyl)-3-(methylthio)-1,2,4-triazin-5(4h)-one。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

苯嗪草酮文献

Absorption, translocation and metabolism of metamitron in Chenopodium album.

Pest Manag. Sci. 68(2) , 209-16, (2012)

In recent years, common lambsquarters (Chenopodium album L.) populations from sugar beet fields in different European countries have responded as resistant to the as-triazinone metamitron. The populat...

Spectroscopic investigation and hydrogen-bonding analysis of triazinones.

J. Mol. Model. 18(8) , 3587-608, (2012)

NIR FT-Raman, FTIR and UV-vis spectra of the herbicide metamitron were recorded and analyzed. The aromaticities, equilibrium geometries, bonding features, electrostatic potentials, and harmonic vibrat...

Chlorophyll fluorescence protocol for quick detection of triazinone resistant Chenopodium album L.

Commun. Agric. Appl. Biol. Sci. 75(2) , 83-90, (2010)

Sugar beet growers in Europe are more often confronted with an unsatisfactory control of Chenopodium album L. (fat-hen), possibly due to the presence of a triazinone resistant biotype. So far, two mut...

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