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2-氟-4-硝基苯甲醚

2-氟-4-硝基苯甲醚名称

[ CAS 号 ]:
455-93-6

[ 中文名 ]:
2-氟-4-硝基苯甲醚

[ 英文名 ]:
2-Fluoro-4-nitroanisole

[中文别名 ]:

[英文别名 ]:

MFCD00061095
2-Fluoro-1-methoxy-4-nitrobenzene
2-Fluoro-4-Nitroanisole

2-氟-4-硝基苯甲醚物理化学性质

[ 密度 ]:
1.321 g/cm3

[ 沸点 ]:
277.2ºC at 760 mmHg

[ 熔点 ]:
103-105 °C(lit.)

[ 分子式 ]:
C₇H₆FNO₃

[ 分子量 ]:
171.12600

[ 闪点 ]:
121.4ºC

[ 精确质量 ]:
171.03300

[ PSA ]:
55.05000

[ LogP ]:
2.26570

[ 外观性状 ]:
黄色粉末

[ 蒸汽压 ]:
0.000519mmHg at 25°C

[ 折射率 ]:
1.552

[ 储存条件 ]:
室温

2-氟-4-硝基苯甲醚MSDS

2-氟-4-硝基苯甲醚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2909309090

2-氟-4-硝基苯甲醚合成路线

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2-氟-4-硝基苯甲醚海关

[ 海关编码 ]: 2909309090

[ 中文概述 ]:
2909309090 其他芳香醚及其卤化衍生物、磺化、硝化衍生物（包括亚硝化衍生物）。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

2-氟-4-硝基苯甲醚文献

The element effect and nucleophilicity in nucleophilic aromatic photosubstitution (SN2Ar*). Local atom effects as mechanistic probes of very fast reactions.

J. Org. Chem. 73(5) , 1925-34, (2008)

Photoreactions of 4-nitroanisole and the 2-halo-4-nitroanisoles (halogen = F, Cl, Br, and I) with the nucleophiles hydroxide ion and pyridine have been investigated quantitatively to extend the findin...

The photosubstitution of 2-fluoro-4-nitroanisole with n-hexylamine. Evidence of two different triplet excited states in a dual mechanistic pathway. Pleixats R and Marquet J.

Tetrahedron 46(4) , 1343-52, (1990)

The Search for Biochemical Photoprobes. III. The Photoreactions of 4-Nitroveratrole and 2-Fluoro-4-nitroanisole with Bovine Pancreatic Ribonuclease A and with Model Nucleophiles. Marquet J, et al.

Tetrahedron 49(6) , 1297-1306, (1993)

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