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苯基三氟甲基硫醚

苯基三氟甲基硫醚名称

[ CAS 号 ]:
456-56-4

[ 中文名 ]:
三氟甲基苯硫醚

[ 英文名 ]:
((trifluoromethyl)thio)benzene

[中文别名 ]:

[英文别名 ]:

MFCD00040839
(Trifluoromethylthio)Benzene
trifluoromethylsulfanylbenzene
Sulfide phenyl trifluoromethyl
Benzene, [(trifluoromethyl)thio]-
[(Trifluoromethyl)sulfanyl]benzene
Phenyl trifluoromethyl sulfide
EINECS 207-270-0
α,α,α-Trifluorothioanisole
((trifluoromethyl)thio)benzene

苯基三氟甲基硫醚物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
106.2±40.0 °C at 760 mmHg

[ 分子式 ]:
C₇H₅F₃S

[ 分子量 ]:
178.175

[ 闪点 ]:
18.0±27.3 °C

[ 精确质量 ]:
178.006409

[ PSA ]:
25.30000

[ LogP ]:
3.57

[ 外观性状 ]:
无色和透明液体

[ 蒸汽压 ]:
33.3±0.2 mmHg at 25°C

[ 折射率 ]:
1.494

[ 储存条件 ]:
室温

苯基三氟甲基硫醚MSDS

详细MSDS(安全技术说明书)

苯基三氟甲基硫醚安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T: Toxic;

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16-S36-S36/37/39-S23

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2930909090

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苯基三氟甲基硫醚海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

苯基三氟甲基硫醚文献

Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones.

J. Org. Chem. 11th ed., 68 , 4457-4463, (2003)

A new and efficient method for the preparation of tri- and difluoromethylsilanes using magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes is reported using tri- and diflu...

Synthesis of sulfoxides by the hydrogen peroxide induced oxidation of sulfides catalyzed by iron tetrakis(pentafluorophenyl)porphyrin: scope and chemoselectivity.

J. Org. Chem. 10th ed., 69 , 3586-3589, (2004)

The oxidation of sulfides with H(2)O(2) catalyzed by iron tetrakis(pentafluorophenyl)porphyrin in EtOH is an efficient and chemoselective process. With a catalyst concentration 0.03-0.09% of that of t...

Synthesis and structure-activity relationships of benzophenone hydrazone derivatives with insecticidal activity.

Pest Manag. Sci. 2nd ed., 57 , 191-202, (2001)

A broad range of benzophenone hydrazone derivatives was prepared and tested against selected chewing insect pests, allowing the analysis of structure-activity relationships. Good activity was found on...

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