乐杀螨
乐杀螨用途
非内吸性杀螨剂、杀菌剂。农药分析标准。
乐杀螨名称
[ CAS 号 ]:
485-31-4
[ 中文名 ]:
乐杀螨
[ 英文名 ]:
Binapacryl
[中文别名 ]:
[英文别名 ]:
- 2-sec-Butyl-4,6-dinitrophenyl 3-methylbut-2-enoate
- Morocide
- MFCD00055425
- Caswell No. 086
- Dinoseb methacrylate
- 2-sec-Butyl-4,6-dinitrophenyl 3,3-Dimethylacrylate
- 2-sec-butyl-4,6-dinitrophenyl-3,3-dimethylacrylate
- Dapacryl
- Morrocid
- EINECS 207-612-9
乐杀螨物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
436.7±45.0 °C at 760 mmHg
[ 熔点 ]:
68-69ºC
[ 分子式 ]:
C15H18N2O6
[ 分子量 ]:
322.313
[ 闪点 ]:
171.7±30.7 °C
[ 精确质量 ]:
322.116486
[ PSA ]:
117.94000
[ LogP ]:
4.90
[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C
[ 折射率 ]:
1.553
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
乐杀螨MSDS
乐杀螨毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- GQ5600000
- CHEMICAL NAME :
- Crotonic acid, 3-methyl-, 2-sec-butyl-4,6-dinitrophenyl ester
- CAS REGISTRY NUMBER :
- 485-31-4
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- C15-H18-N2-O6
- MOLECULAR WEIGHT :
- 322.35
- WISWESSER LINE NOTATION :
- 2Y1&R CNW ENW BOV1UY1&1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 58 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 720 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 1600 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 750 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - dog
- DOSE/DURATION :
- 50 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 750 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 200 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Bird - chicken
- DOSE/DURATION :
- >800 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 5 mg/plate
- REFERENCE :
- MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 116,185,1983
乐杀螨安全信息
[ 符号 ]:
GHS07, GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H302 + H312-H360D-H410
[ 警示性声明 ]:
P201-P273-P280-P308 + P313-P501
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;
[ 风险声明 (欧洲) ]:
61-21/22-50/53
[ 安全声明 (欧洲) ]:
53-45-60-61
[ 危险品运输编码 ]:
2779
[ WGK德国 ]:
3
[ RTECS号 ]:
GQ5600000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
乐杀螨制备
2-仲丁基-4,6-二硝基酚与β,β二甲基丙烯酰氯在氮气保护下,于 135 ℃ 搅拌反应5h,减压蒸馏除去过量的酰氯,剩余物用石油醚洗涤,经苯-己烷重结晶,得原药乐杀螨。原料消耗定额:2-仲丁基-4,6-二硝基酚 750kg /t、β,β二甲基丙烯酰氯 1120kg /t。
乐杀螨文献
Arh. Hig. Rada Toksikol. 40(3) , 277-83, (1989)
The effects of various pesticides (lindane, binapacrile and parathion) on the content of cytochrome P450 and glutathione, and on the activity of lipoperoxidase, xanthine oxidase and transaminases (SGO...
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相关化合物
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