氧化偶氮苯

【用途一】
有机合成中间体。

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
336.0±25.0 °C at 760 mmHg

[ 熔点 ]:
32-36 °C

[ 分子式 ]:
C₁₂H₁₀N₂O

[ 分子量 ]:
198.221

[ 闪点 ]:
157.0±23.2 °C

[ 精确质量 ]:
198.079315

[ PSA ]:
41.11000

[ LogP ]:
4.09

[ 外观性状 ]:
固体;Light yellow to Amber to Dark green powder to crystal

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.582

[ 储存条件 ]:
通风低温干燥

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

CO4025000

CHEMICAL NAME :

Azoxybenzene

CAS REGISTRY NUMBER :

495-48-7

LAST UPDATED :

199806

DATA ITEMS CITED :

20

MOLECULAR FORMULA :

C12-H10-N2-O

MOLECULAR WEIGHT :

198.24

WISWESSER LINE NOTATION :

ONR&UNR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

620 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

940 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

515 mg/kg

TOXIC EFFECTS :

Gastrointestinal - other changes Liver - other changes

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

500 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

1350 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

275 mg/kg

TOXIC EFFECTS :

Gastrointestinal - other changes Kidney, Ureter, Bladder - other changes

TYPE OF TEST :

Micronucleus test

TYPE OF TEST :

Cytogenetic analysis

TYPE OF TEST :

Sperm Morphology

MUTATION DATA

TYPE OF TEST :

Morphological transformation

TEST SYSTEM :

Rodent - hamster Kidney

DOSE/DURATION :

33400 ug/L

REFERENCE :

PMRSDJ Progress in Mutation Research. (Elsevier Science Pub. Co., Inc., 52 Vanderbilt Ave., New York, NY 10017) V.1- 1981- Volume(issue)/page/year: 1,626,1981

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H332

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R20/22

[ 安全声明 (欧洲) ]:
S28A-S28

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
CO4025000

[ 海关编码 ]:
2927000090

详细合成路线

硝基苯经还原而得。在反应锅内投入硝基苯、氢氧化钠溶液，升温至60℃，慢慢加入葡萄糖液，在65-75℃下保温1h，即反应生成氧化偶氮苯。实验室制备实例：在带回流装置的500ml烧瓶中，加入30g氢氧化钠和100ml水配成的溶液，再加入20.5g纯的硝基苯，在水浴中加热，温度保持在55-60℃。在搅拌下分多次加入总量为21g的无水葡萄糖，约1h加完。在沸水浴中加热2h。然后将热的反应物进行水蒸气蒸馏，除去未反应的硝基苯和反应副产物苯胺。当馏出液呈澄清时（约蒸出1L），将剩余物倒入烧杯中，冰浴冷却。反应物很快凝固，将其研碎、水洗，在滤纸上晾干，得13g纯品，熔点35-35.5℃，产率79%，有乙醇重结晶，熔点为36℃。

[ 海关编码 ]: 2927000090

[ 中文概述 ]:
2927000090 其他重氮化合物、偶氮化合物等（包括氧化偶氮化合物）. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Reduction of nitroarenes to azoxybenzenes by potassium borohydride in water.

Molecules 16 , 3563-3568, (2011)

The synthesis of the azoxybenzenes by the reduction of nitroarenes with reducing agent potassium borohydride in water was reported for the first time. PEG-400 was used as a phase transfer catalyst and...

[A case of suicide suspected of poisoning from taking some agricultural chemicals].

Nihon Hoigaku. Zasshi 45(2) , 158-65, (1991)

Forensic toxicological examination was performed on a person who was suspected of poisoning by Azomite emulsion (an acaricide), Roundup (a herbicide) and/or unidentified agricultural chemical and died...

[Distribution and metabolism of azoxybenzene in the rat].

Z. Gesamte Hyg. 35(5) , 255-7, (1989)

No sex differences could been shown after absorption and distribution of azoxybenzen in the rat. The highest level occur in the thyroid gland, the adrenals and in the fat tissues. The maximum level wa...

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公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：氧化偶氮苯

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥2768.0/100g ￥958.0/25g

联系人：刘佳

产品详情：氧化偶氮苯

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公司名：上海创赛科技有限公司

区域：上海市嘉定区

价格：
￥1976.0/100g

联系人：夏言

产品详情：[Perfemiker]氧化偶氮苯,≥98.0%(GC)

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥381.9/10g ￥762.9/25g ￥293.9/5g ￥2634.9/100g

联系人：阿拉丁

产品详情：氧化偶氮苯

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