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1,3-环己二酮

1,3-环己二酮用途

环己烷-1,3-二酮是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

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1,3-环己二酮名称

[ CAS 号 ]:
504-02-9

[ 中文名 ]:
1,3-环己二酮

[ 英文名 ]:
1,3-Cyclohexanedione

[中文别名 ]:

[英文别名 ]:

cyclohexane-1,3-dione
Dihydroresorcinol
EINECS 207-980-0
1,3-Cyclohexanedione
MFCD00001585

1,3-环己二酮生物活性

[ 描述 ]:

环己烷-1,3-二酮是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

1,3-环己二酮物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
235.1±23.0 °C at 760 mmHg

[ 熔点 ]:
101-105 °C(lit.)

[ 分子式 ]:
C₆H₈O₂

[ 分子量 ]:
112.13

[ 闪点 ]:
85.7±19.6 °C

[ 精确质量 ]:
112.052429

[ PSA ]:
34.14000

[ LogP ]:
-0.89

[ 外观性状 ]:
米色结晶粉末

[ 蒸汽压 ]:
0.1±0.5 mmHg at 25°C

[ 折射率 ]:
1.474

[ 储存条件 ]:
2-8°C

[ 水溶解性 ]:
soluble

1,3-环己二酮MSDS

1,3-环己二酮安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
GV0350000

[ 海关编码 ]:
2914399090

1,3-环己二酮合成路线

1,3-环己二酮上下游产品

1,3-环己二酮上游产品

1,3-环己二酮下游产品

1,3-环己二酮制备

将间苯二酚与氢氧化钠溶液投入压热釜，加入镍催化剂，在50℃、70-100大气压通氢反应10-12h。然后降温、泄压，滤除催化剂，滤液用浓盐酸酸化，冷至0℃，滤出结晶，即1,3-环己二酮粗品。粗品用热苯重结晶，得成品。其制备方法是用间苯二酚在兰尼镍催化剂存在下进行加氢反应而得到产品。

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1,3-环己二酮海关

[ 海关编码 ]: 2914299000

[ 中文概述 ]:
2914299000. 其他不含其他含氧基的环烷酮、环烯酮或环萜烯酮. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
2914299000. other cyclanic, cyclenic or cyclotherpenic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

1,3-环己二酮文献

Identification and characterization of novel benzil (diphenylethane-1,2-dione) analogues as inhibitors of mammalian carboxylesterases.

J. Med. Chem. 48 , 2906-15, (2005)

Carboxylesterases (CE) are ubiquitous enzymes responsible for the metabolism of xenobiotics. Because the structural and amino acid homology among esterases of different classes, the identification of ...

[Reaction of pyridinium and quinolinium salts having the leaving group at the 2- or 4-position with active methylene compounds].

Yakugaku Zasshi 126(2) , 99-108, (2006)

The reactions of 2- or 4-cyanopyridinium salts with active methylene compounds such as dimethyl malonate, malononitrile, and cyclohexane-1,3-dione affording 2- or 4-(substituted methylene) pyridines a...

Dimeric cyclohexane-1,3-dione oximes inhibit wheat acetyl-CoA carboxylase and show anti-malarial activity.

Bioorg. Med. Chem. Lett. 20 , 4611-3, (2010)

A series of dimeric 1,3-cyclohexanedione oxime ethers were synthesized and found to have significant antiplasmodial activity with IC(50)'s in the range 3-12 microM. The most active dimer was tested in...

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