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N-羟基邻苯二甲酰亚胺

N-羟基邻苯二甲酰亚胺用途

用作阿米卡星等药物中间体

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N-羟基邻苯二甲酰亚胺名称

[ CAS 号 ]:
524-38-9

[ 中文名 ]:
N-羟基邻苯二甲酰亚胺

[ 英文名 ]:
N-Hydroxyphthalimide

[中文别名 ]:

[英文别名 ]:

nhpi
N-Hydroxy Phthalimide
2-Hydroxy-1H-isoindole-1,3(2H)-dione
2-hydroxyisoindoline-1,3-dione
N-Hydroxyphthalimide
HOPHT
EINECS 208-358-1
N-hydroxylphthalimide
phthalamohydroxamic acid
PHTHALOXIME

N-羟基邻苯二甲酰亚胺物理化学性质

[ 密度 ]:
1.6±0.1 g/cm3

[ 沸点 ]:
370.3±25.0 °C at 760 mmHg

[ 熔点 ]:
233 °C (dec.)(lit.)

[ 分子式 ]:
C₈H₅NO₃

[ 分子量 ]:
163.130

[ 闪点 ]:
177.8±23.2 °C

[ 精确质量 ]:
163.026947

[ PSA ]:
57.61000

[ LogP ]:
0.42

[ 外观性状 ]:
黄色潮湿的粉末

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.718

[ 储存条件 ]:
Store at RT.

N-羟基邻苯二甲酰亚胺MSDS

N-羟基邻苯二甲酰亚胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TI5200000

CHEMICAL NAME :: Phthalimide, N-hydroxy-

CAS REGISTRY NUMBER :: 524-38-9

BEILSTEIN REFERENCE NO. :: 0131208

LAST UPDATED :: 199709

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C8-H5-N-O3

MOLECULAR WEIGHT :: 163.14

WISWESSER LINE NOTATION :: T56 BVNVJ CQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 178 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#00747

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N-羟基邻苯二甲酰亚胺安全信息

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
TI5200000

[ 海关编码 ]:
29251995

N-羟基邻苯二甲酰亚胺合成路线

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N-羟基邻苯二甲酰亚胺海关

[ 海关编码 ]: 2925190090

[ 中文概述 ]:
2925190090 其他酰亚胺及其衍生物盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

N-羟基邻苯二甲酰亚胺文献

Bromide-free oxidizing system for carboxylic moiety formation in cellulose chain.

Carbohydr. Polym. 90(4) , 1415-9, (2012)

NHPI (N-hydroxyphthalimide) was used to mediate the oxidation of cellulose fibers in the absence of sodium bromide, as traditionally was used in this kind of transformations, solely using sodium hypoc...

Anthrone-derived NHPI analogues as catalysts in reactions using oxygen as an oxidant.

Org. Biomol. Chem. 6(22) , 4096-8, (2008)

An enantioselective synthesis of anthrone-derived NHPI analogues has been developed. One of these analogues, in combination with Co salts, was employed to catalyse the aerobic oxidation of benzylic co...

Oxidized cellulose--survey of the most recent achievements.

Carbohydr. Polym. 93(1) , 207-15, (2013)

The functionalization and particularly the oxidation of cellulose is an intriguing and challenging topic due to the presence of multiple reactive sites, which can undergo specific reactions. The varie...

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