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溴乙酸叔丁酯

溴乙酸叔丁酯用途

【用途一】
用作医药中间体，用于合成氨基酸和肽类化合物
【用途二】
常规烷基化试剂，用于合成胶原酶抑制剂(S,S,R)-(-)-actinonin；乙酸叔丁酯中间体等等。

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溴乙酸叔丁酯名称

[ CAS 号 ]:
5292-43-3

[ 中文名 ]:
溴乙酸叔丁酯

[ 英文名 ]:
2-Methyl-2-propanyl bromoacetate

[中文别名 ]:

[英文别名 ]:

Bromoacetic Acid tert-Butyl Ester
E1VOX1&1&1
2-Methyl-2-propanyl bromoacetate
tert-butyl 2-bromoacetate
tert-Butyl Bromoacetate
EINECS 226-133-6
Acetic acid, 2-bromo-, 1,1-dimethylethyl ester
Acetic acid, bromo-, 1,1-dimethylethyl ester
MFCD00000188
T-BUTYL 2-BROMOACETATE

溴乙酸叔丁酯物理化学性质

[ 密度 ]:
1.4±0.1 g/cm3

[ 沸点 ]:
164.0±8.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₁₁BrO₂

[ 分子量 ]:
195.054

[ 闪点 ]:
49.4±0.0 °C

[ 精确质量 ]:
193.994232

[ PSA ]:
26.30000

[ LogP ]:
2.07

[ 外观性状 ]:
略黄色透明液体

[ 蒸汽压 ]:
2.0±0.3 mmHg at 25°C

[ 折射率 ]:
1.457

[ 储存条件 ]:
0-6°C

溴乙酸叔丁酯MSDS

溴乙酸叔丁酯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R10;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S24/25-S16

[ 危险品运输编码 ]:
UN 1993 3/PG 3

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3

[ 海关编码 ]:
2915709000

溴乙酸叔丁酯合成路线

溴乙酸叔丁酯上下游产品

溴乙酸叔丁酯上游产品

溴乙酸叔丁酯下游产品

溴乙酸叔丁酯海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

溴乙酸叔丁酯文献

Gas chromatography with parallel hard and soft ionization mass spectrometry.

Rapid Commun. Mass Spectrom. 29(1) , 91-9, (2014)

Mass spectrometric identification of compounds in chromatography can be obtained from molecular masses from soft ionization mass spectrometry techniques such as field ionization (FI) and fragmentation...

Preoperative Detection and Intraoperative Visualization of Brain Tumors for More Precise Surgery: A New Dual-Modality MRI and NIR Nanoprobe.

Small 11 , 4517-25, (2015)

In clinical practice, it is difficult to identify tumor margins during brain surgery due to its inherent infiltrative character. Herein, a unique dual-modality nanoprobe (Gd-DOTA-Ag2S QDs, referred as...

Synthesis of fused heteroarylprolines and pyrrolopyrroles.

J. Org. Chem. 69 , 4656-4662, (2004)

Fused heteroarylprolines were prepared starting from 4-oxo-N-(PhF)proline benzyl ester (6, PhF = 9-(9-phenylfluorenyl)) following two approaches. First, allylation of oxoproline 6 followed by Wacker o...

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