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4-羟基哌啶

4-羟基哌啶用途

【用途一】
用在铜催化的N-对抗O-芳基化

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4-羟基哌啶名称

[ CAS 号 ]:
5382-16-1

[ 中文名 ]:
4-羟基哌啶

[ 英文名 ]:
4-Piperidinol

[中文别名 ]:

[英文别名 ]:

4-Hydroxypiperidine
piperdin-4-ol
4-Piperidinol
4PPOL
EINECS 226-373-1
4-Hydropiperidine
MFCD00005999
AURORA KA-1006
4-piperidinyl
4-hydroxy-piperidine

4-羟基哌啶物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
222.0±0.0 °C at 760 mmHg

[ 熔点 ]:
86-90 °C

[ 分子式 ]:
C₅H₁₁NO

[ 分子量 ]:
101.147

[ 闪点 ]:
107.8±0.0 °C

[ 精确质量 ]:
101.084061

[ PSA ]:
32.26000

[ LogP ]:
-0.52

[ 外观性状 ]:
黄色至黄色-橙色潮湿的固体

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.475

[ 储存条件 ]:
Room temperature.

[ 水溶解性 ]:
soluble

4-羟基哌啶MSDS

详细MSDS(安全技术说明书)

4-羟基哌啶安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36-S37/39

[ 危险品运输编码 ]:
3263

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2933322000

4-羟基哌啶上下游产品

4-羟基哌啶上游产品

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4-羟基哌啶海关

[ 海关编码 ]: 2933399090

[ 中文概述 ]:
2933399090. 其他结构含非稠合吡啶环的化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

4-羟基哌啶文献

Synthesis of novel IP agonists via N-aminoethyl cyclic amines prepared by decarboxylative ring-opening reactions.

Molecules 17(2) , 1233-46, (2012)

An efficient synthesis of a highly potent and selective IP (PGI(2) receptor) agonist that is not structurally analogous to PGI(2) is described. This synthesis is accomplished through the following key...

N- versus O-arylation of aminoalcohols: orthogonal selectivity in copper-based catalysts.

J. Am. Chem. Soc. 129 , 3490, (2007)

The spectroscopic (FT-IR, FT-IR gas phase, FT-Raman and UV) and NBO analysis of 4-Hydroxypiperidine by density functional method.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 75(3) , 941-52, (2010)

In this work, we report a combined experimental and theoretical study on molecular structure, vibrational spectra, NBO and UV-spectral analysis of 4-Hydroxypiperidine (4-HP). The FT-IR solid phase (40...

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