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1-氯丙烷

1-氯丙烷用途

用作有机合成中间体及溶剂。

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1-氯丙烷名称

[ CAS 号 ]:
540-54-5

[ 中文名 ]:
1-氯丙烷

[ 英文名 ]:
1-Chloropropane

[中文别名 ]:

[英文别名 ]:

1-Chloropropane
Chloropropane
1-chloro-propane
EINECS 208-749-7
1-chloro-propan
monochloropropane
Propane, 1-chloro-
N-Propyl chloride
Propylchlorid
1-chloro-n-propane

1-氯丙烷物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
46.8±3.0 °C at 760 mmHg

[ 熔点 ]:
-123 °C

[ 分子式 ]:
C₃H₇Cl

[ 分子量 ]:
78.541

[ 闪点 ]:
-31.7±0.0 °C

[ 精确质量 ]:
78.023628

[ LogP ]:
2.03

[ 外观性状 ]:
透明无色液体

[ 蒸汽密度 ]:
2.71 (vs air)

[ 蒸汽压 ]:
343.5±0.1 mmHg at 25°C

[ 折射率 ]:
1.382

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 水溶解性 ]:
2.7 g/L (20 ºC)

1-氯丙烷MSDS

1-氯丙烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX4400000

CHEMICAL NAME :: Propane, 1-chloro-

CAS REGISTRY NUMBER :: 540-54-5

BEILSTEIN REFERENCE NO. :: 1730771

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C3-H7-Cl

MOLECULAR WEIGHT :: 78.55

WISWESSER LINE NOTATION :: G3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 101,321,1982 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 133 gm/m3/30M/1W-I

TOXIC EFFECTS :: Liver - other changes

REFERENCE :: JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 80,139,1944 *** REVIEWS *** TOXICOLOGY REVIEW FAZMAE Fortschritte der Arzneimittelforschung. Progress in Drug Research. (Birkhauser Boston, Inc., c/o Springer-Verlag New York, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1959- Volume(issue)/page/year: 18,365,1974 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4414 No. of Facilities: 10 (estimated) No. of Industries: 2 No. of Occupations: 7 No. of Employees: 173 (estimated) No. of Female Employees: 3 (estimated)

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1-氯丙烷安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H312-H332

[ 警示性声明 ]:
P210-P280

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
F:Flammable;Xn:Harmful;

[ 风险声明 (欧洲) ]:
R11;R20/21/22

[ 安全声明 (欧洲) ]:
S9-S29

[ 危险品运输编码 ]:
UN 1278 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TX4400000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

[ 海关编码 ]:
2903199000

1-氯丙烷合成路线

1-氯丙烷上下游产品

1-氯丙烷上游产品

1-氯丙烷下游产品

1-氯丙烷制备

由正丙醇与盐酸反应而得。将无水氯化锌溶解在盐酸中，搅拌下慢慢加入正丙醇。加完后回流反应，将生成的氯丙烷蒸出，至115-120℃蒸出全部氯丙烷。蒸出的粗品用工业硫酸洗涤、水洗涤、10%碳酸钠洗涤，再用水洗涤，经氯化钙干燥后进行分馏，收集44.6-47.5℃馏分即得成品。另外，正丙醇与五氯化磷反应也可制备氯丙烷。

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1-氯丙烷海关

[ 海关编码 ]: 2903199000

[ 中文概述 ]:
2903199000 其他无环烃的饱和氯化衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:5.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

1-氯丙烷文献

QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES.

Eur. J. Med. Chem. 43 , 714-40, (2008)

Simplified molecular input line entry system (SMILES) has been utilized in constructing quantitative structure-property relationships (QSPR) for octanol/water partition coefficient of vitamins and org...

Photosensitized degradation kinetics of trace halogenated contaminants in natural waters using membrane introduction mass spectrometry as an in situ reaction monitor.

Photochem. Photobiol. Sci. 14 , 2108-18, (2015)

The photochemically mediated dechlorination of polyhalogenated compounds represents a potential decontamination strategy and a relevant environmental process in chemically reducing media. We report th...

Phosphatidylcholine-fatty Alcohols Equilibria in Monolayers at the Air/Water Interface.

J. Membr. Biol. 248 , 767-73, (2015)

Monolayers of phosphatidylcholine (PC), tetradecanol (TD), hexadecanol (HD), octadecanol (OD) and eicosanol (E) and their binary mixtures were investigated at the air/water interface. The surface tens...

更多文献

1-氯丙烷

1-氯丙烷用途

1-氯丙烷名称

1-氯丙烷物理化学性质

1-氯丙烷MSDS

详细MSDS(安全技术说明书)

1-氯丙烷毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

1-氯丙烷安全信息

1-氯丙烷合成路线

详细合成路线

1-氯丙烷上下游产品

1-氯丙烷上游产品

1-氯丙烷下游产品

1-氯丙烷制备

1-氯丙烷海关

1-氯丙烷文献

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