氯甲酸癸酯

氯甲酸癸酯用途

Decyl chloroformate is an n-alkyl chloroformate derivative that can be prepared by reacting decyl alcohol with triphosgene. Decyl chloroformate may be used in the preparation of (S)-(+)-N-decoxycarbonyl-leucine, a chiral surfactant. It may also be used to synthesize decyl chloride via decarboxylation in the presence of dimethylformamide.

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氯甲酸癸酯名称

[ CAS 号 ]:
55488-51-2

[ 中文名 ]:
癸氯

[ 英文名 ]:
Decyl chloroformate

[中文别名 ]:

氯甲酸(N-癸基)酯

[英文别名 ]:

decyloxycarbonyl chloride
MFCD00126853
n-decyl chloroformate
decanyl chloroformate
Chloroformic Acid Decyl Ester
EINECS 259-668-9
Decyl chloroformate
chloroformic acid n-decyl ester
chlorocarbonic acid decyl ester

氯甲酸癸酯物理化学性质

[ 密度 ]:
0.956 g/mL at 25ºC(lit.)

[ 沸点 ]:
226-227ºC(lit.)

[ 分子式 ]:
C₁₁H₂₁ClO₂

[ 分子量 ]:
220.73600

[ 闪点 ]:
>230 °F

[ 精确质量 ]:
220.12300

[ PSA ]:
26.30000

[ LogP ]:
4.50250

[ 外观性状 ]:
液体;Colorless to Almost colorless clear liquid

[ 折射率 ]:
n20/D 1.438(lit.)

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)

氯甲酸癸酯MSDS

详细MSDS(安全技术说明书)

氯甲酸癸酯安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C

[ 风险声明 (欧洲) ]:
34

[ 安全声明 (欧洲) ]:
S26-S27-S36-S37-S39

[ 危险品运输编码 ]:
UN 1760 8/PG 1

[ 海关编码 ]:
2915900090

氯甲酸癸酯合成路线

详细合成路线

氯甲酸癸酯海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

氯甲酸癸酯文献

Carbamate chiral surfactants for capillary electrophoresis. Ding W and Fritz JS.

J. Chromatogr. A. 831(2) , 311-320, (1999)

Dimethylformamide-catalyzed decarboxylation of alkyl chloroformates. A synthesis of primary alkyl chlorides. Richter R and Tucker B.

J. Org. Chem. 48(15) , 2625-2627, (1983)

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