苯并(a)蒽
苯并(a)蒽用途
对环境和水体有害,用于环境检测。
【用途二】
本品在工业上无生产和使用价值,一般只作为生产过程中形成的副产物随废气排放。
苯并(a)蒽名称
[ CAS 号 ]:
56-55-3
[ 中文名 ]:
苯并[a]蒽
[ 英文名 ]:
Benz(a)anthracene
[中文别名 ]:
[英文别名 ]:
- Benz[a]anthracene
- Benzanthracene
- Benzo[b]phenanthrene
- 1,2-Benzanthracene
- benzo[a]anthracene
- Tetraphene
- MFCD00003599
- 1,2-Benz[a]anthracene
- EINECS 200-280-6
- Benz(a)anthracene
苯并(a)蒽物理化学性质
[ 密度 ]:
1.2±0.1 g/cm3
[ 沸点 ]:
436.7±12.0 °C at 760 mmHg
[ 熔点 ]:
157-159 °C(lit.)
[ 分子式 ]:
C18H12
[ 分子量 ]:
228.288
[ 闪点 ]:
209.1±13.7 °C
[ 精确质量 ]:
228.093903
[ LogP ]:
5.91
[ 外观性状 ]:
固体;White to Yellow to Green powder to crystaline
[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C
[ 折射率 ]:
1.771
[ 储存条件 ]:
通风低温干燥,与库房食品原料分开存放
[ 稳定性 ]:
Stable. Combustible. Incompatible with strong oxidizing agents.
苯并(a)蒽MSDS
苯并(a)蒽毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CV9275000
- CHEMICAL NAME :
- Benz(a)anthracene
- CAS REGISTRY NUMBER :
- 56-55-3
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 84
- MOLECULAR FORMULA :
- C18-H12
- MOLECULAR WEIGHT :
- 228.30
- WISWESSER LINE NOTATION :
- L D6 B666J
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >200 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 10 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 18 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Skin and Appendages - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Implant
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 80 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 18 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 360 mg/kg/56W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 240 mg/kg/1W-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Skin and Appendages - tumors
- TYPE OF TEST :
- Specific locus test
- TYPE OF TEST :
- Specific locus test
- TYPE OF TEST :
- DNA repair
- TYPE OF TEST :
- Sex chromosome loss and nondisjunction
- TYPE OF TEST :
- Micronucleus test
- TYPE OF TEST :
- Micronucleus test
- TYPE OF TEST :
- Morphological transformation
- TYPE OF TEST :
- DNA adduct
- TYPE OF TEST :
- Sister chromatid exchange
- TYPE OF TEST :
- Micronucleus test
- TYPE OF TEST :
- DNA adduct
- TYPE OF TEST :
- Micronucleus test
- TYPE OF TEST :
- Cytogenetic analysis
- TYPE OF TEST :
- Sister chromatid exchange
MUTATION DATA
- TEST SYSTEM :
- Rodent - hamster
- DOSE/DURATION :
- 900 mg/kg/24H
- REFERENCE :
- AMSHAR Acta Morphologica Academiae Scientiarum Hungaricae. (Budapest, Hungary) V.1-30, 1951-82. Volume(issue)/page/year: 27,199,1979 *** REVIEWS *** ACGIH TLV-Suspected human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 3,45,1973 IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,135,1983 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 32,135,1983 IARC Cancer Review:Group 2A IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 TOXICOLOGY REVIEW AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 23,6,1971 TOXICOLOGY REVIEW ACRSAJ Advances in Cancer Research. (Academic Press, Inc., 465 S. Lincoln Dr., Troy, MO 63379) V.1- 1953- Volume(issue)/page/year: 7,475,1963 TOXICOLOGY REVIEW 85DHAX "Medical and Biologic Effects of Environmental Pollutants Series," Washington, DC, National Academy of Sciences, 1972-77 Volume(issue)/page/year: Pc,4,1972 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-FRANCE;Carcinogen JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - B0045 No. of Facilities: 149 (estimated) No. of Industries: 4 No. of Occupations: 4 No. of Employees: 2311 (estimated)
苯并(a)蒽安全信息
[ 符号 ]:
GHS08, GHS09
[ 信号词 ]:
Danger
[ 危害声明 ]:
H350-H410
[ 警示性声明 ]:
P201-P273-P308 + P313-P501
[ 靶器官 ]:
Blood, Central nervous system, Liver
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
T,N,Xn,F
[ 风险声明 (欧洲) ]:
R45;R50/53;
[ 安全声明 (欧洲) ]:
S53-S45-S60-S61-S62-S36/37-S24/25-S23
[ 危险品运输编码 ]:
UN 3077 9/PG 3
[ WGK德国 ]:
3
[ RTECS号 ]:
CV9275000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1(b)
苯并(a)蒽上下游产品
苯并(a)蒽上游产品
苯并(a)蒽下游产品
苯并(a)蒽制备
1.本品存在于煤焦油、煤焦油沥青、杂酚油中,炼焦、各种烧煤烟道气、汽车发动机排气以及碳水化合物、氨基酸和酯肪酸在700℃热解均有苯并(a)蒽存在。
2. 从冰醋酸或乙醇中得片状体。
苯并(a)蒽文献
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UV-polymerized butyl methacrylate monoliths with embedded carboxylic single-walled carbon nanotubes for CEC applications.Anal. Bioanal. Chem 406(25) , 6329-36, (2014)
The preparation of polymeric monoliths with embedded carboxy-modified single-walled carbon nanotubes (c-SWNTs) and their use for capillary electrochromatography (CEC) is described. Carbon nanotube com...
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