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甲氧基丙酮

甲氧基丙酮用途

【用途一】
用作农药中间体，可生产异丙甲草胺
【用途二】
用于农药中间体，可生产异丙甲草胺。

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甲氧基丙酮名称

[ CAS 号 ]:
5878-19-3

[ 中文名 ]:
1-甲氧基-2-丙酮

[ 英文名 ]:
1-Methoxyacetone

[中文别名 ]:

[英文别名 ]:

MFCD00008768
1-Methoxyacetone
EINECS 227-549-0
1-methoxypropan-2-one
2-Propanone, 1-methoxy-

甲氧基丙酮物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
118.9±13.0 °C at 760 mmHg

[ 熔点 ]:
78ºC

[ 分子式 ]:
C₄H₈O₂

[ 分子量 ]:
88.105

[ 闪点 ]:
25.0±0.0 °C

[ 精确质量 ]:
88.052429

[ PSA ]:
26.30000

[ LogP ]:
-0.53

[ 外观性状 ]:
透明淡黄色至黄色液体

[ 蒸汽压 ]:
16.3±0.2 mmHg at 25°C

[ 折射率 ]:
1.373

[ 储存条件 ]:
Flammables area

[ 水溶解性 ]:
miscible

甲氧基丙酮MSDS

甲氧基丙酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UC2988600

CHEMICAL NAME :: 2-Propanone, 1-methoxy-

CAS REGISTRY NUMBER :: 5878-19-3

BEILSTEIN REFERENCE NO. :: 1560175

LAST UPDATED :: 199710

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C4-H8-O2

MOLECULAR WEIGHT :: 88.12

WISWESSER LINE NOTATION :: 1V1O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,704,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,704,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 8980 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >20 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974

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甲氧基丙酮安全信息

[ 符号 ]:

GHS02

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;F: Flammable;

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S16-S29-S33

[ 危险品运输编码 ]:
UN 1224 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
UC2988600

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2914509090

甲氧基丙酮合成路线

甲氧基丙酮海关

[ 海关编码 ]: 2914509090

[ 中文概述 ]:
2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

甲氧基丙酮文献

Protonation thermochemistry of selected hydroxy- and methoxycarbonyl molecules.

J. Phys. Chem. A 109(51) , 11851-9, (2005)

The gas-phase basicities of a representative set of hydroxy- and methoxycarbonyl compounds (hydroxyacetone, 1, 3-hydroxybutanone, 2, 3-hydroxy-3-methylbutanone, 3, 1-hydroxy-2-butanone, 4, 4-hydroxy-2...

Mechanism of the double aldol reaction: the first spectroscopic characterization of a carbon-bound boron enolate derived from carboxylic esters.

J. Am. Chem. Soc. 124(36) , 10759-64, (2002)

The novel doubly borylated enolate is identified as an intermediate of the double aldol reaction of acetate esters. As a precursor to the formation of the doubly borylated enolate, carbon-bound boron ...

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