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3-溴丙酸

3-溴丙酸用途

【用途一】
用于有机合成

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3-溴丙酸名称

[ CAS 号 ]:
590-92-1

[ 中文名 ]:
3-溴丙酸

[ 英文名 ]:
3-Bromopropanoic acid

[中文别名 ]:

[英文别名 ]:

β-Bromopropanoic acid
EINECS 209-694-1
3-Bromopropionic acid
MFCD00002763
Propanoic acid, 3-bromo-
3-Bromopropanoic acid
PROPIONIC ACID, 3-BROMO-
β-Bromopropionic acid
3-Bromopropionic

3-溴丙酸物理化学性质

[ 密度 ]:
1.8±0.1 g/cm3

[ 沸点 ]:
239.5±23.0 °C at 760 mmHg

[ 熔点 ]:
58-62 °C(lit.)

[ 分子式 ]:
C₃H₅BrO₂

[ 分子量 ]:
152.975

[ 闪点 ]:
65.6±0.0 °C

[ 精确质量 ]:
151.947281

[ PSA ]:
37.30000

[ LogP ]:
0.69

[ 外观性状 ]:
白色至灰白色结晶粉末

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.500

[ 储存条件 ]:
库房通风低温干燥,与食品、氧化剂、碱类分开储运

[ 水溶解性 ]:
0.1 g/mL

3-溴丙酸MSDS

3-溴丙酸毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UE7875000

CHEMICAL NAME :: Propionic acid, 3-bromo-

CAS REGISTRY NUMBER :: 590-92-1

BEILSTEIN REFERENCE NO. :: 1071333

LAST UPDATED :: 199709

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C3-H5-Br-O2

MOLECULAR WEIGHT :: 152.99

WISWESSER LINE NOTATION :: QV2E

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity)

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 580 mg/kg/8W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 25 ug/plate

REFERENCE :: DHEFDK HEW Publication (FDA. United States). (Washington, DC) ?-1979(?). For publisher information, see HPFSDS. Volume(issue)/page/year: FDA-78-1046,1978

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3-溴丙酸安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
F:Flammable;C:Corrosive;

[ 风险声明 (欧洲) ]:
R11;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
UE7875000

[ 包装等级 ]:
III

[ 危险类别 ]:
4.1

[ 海关编码 ]:
2915501000

3-溴丙酸合成路线

3-溴丙酸上下游产品

3-溴丙酸上游产品

3-溴丙酸下游产品

3-溴丙酸制备

由丙烯腈与溴化氢反应制得溴丙腈进而水解而得3-溴丙酸。在沸腾的氢溴酸中加入丙烯腈，在130℃回流反应6h，过滤得到的固体用乙醇提取，回收乙醇后的粗品经减压蒸馏而得。由2-氰乙醇与40%氢溴酸一起加热回流2h，也可生产3-溴丙酸，产率80%以上。

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3-溴丙酸海关

[ 海关编码 ]: 2915900090

[ 中文概述 ]:
2915900090. 其他饱和无环一元羧酸及其酸酐（酰卤、过氧）化物、过氧酸及其卤化、硝化、磺化、亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

3-溴丙酸文献

Multifunctional Magnetic Gd(3+) -Based Coordination Polymer Nanoparticles: Combination of Magnetic Resonance and Multispectral Optoacoustic Detections for Tumor-Targeted Imaging in vivo.

Small 11 , 5675-86, (2015)

To overcome traditional barriers in optical imaging and microscopy, optoacoustic-imaging has been changed to combine the accuracy of spectroscopy with the depth resolution of ultrasound, achieving a n...

A transition-state analysis of the enzyme catalysis in the affinity labelling of horse-liver alcohol dehydrogenase by bromoacids.

Eur. J. Biochem. 126(2) , 247-52, (1982)

The effect of temperature on the inactivation of liver alcohol dehydrogenase and on the alkylation of a model thiol free in solution by bromoacetate, 2-bromopropionate, 3-bromopropionate and 2-bromo-3...

Development of a gas chromatographic test for the quantification of the biomarker 3-bromopropionic acid in human urine.

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 802(2) , 361-6, (2004)

An accurate and precise method was developed for the detection and quantification of 3-bromopropionic acid (3-BPA), a metabolite and biomarker for exposure to 1-bromopropane (1-BP). 1-BP is used as an...

更多文献

3-溴丙酸

3-溴丙酸用途

3-溴丙酸名称

3-溴丙酸物理化学性质

3-溴丙酸MSDS

详细MSDS(安全技术说明书)

3-溴丙酸毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

3-溴丙酸安全信息

3-溴丙酸合成路线

详细合成路线

3-溴丙酸上下游产品

3-溴丙酸上游产品

3-溴丙酸下游产品

3-溴丙酸制备

3-溴丙酸海关

3-溴丙酸文献

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