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3-溴苯酚

3-溴苯酚用途

有机合成中间体

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3-溴苯酚名称

[ CAS 号 ]:
591-20-8

[ 中文名 ]:
间溴苯酚

[ 英文名 ]:
3-Bromophenol

[中文别名 ]:

[英文别名 ]:

M-BROMOPHENOL
3-bromophenyl alcohol
meta-bromophenol
Phenol, 3-bromo-
EINECS 209-706-5
Phenol,3-bromo
Phenol,m-bromo
3-bromo phenol
Bromophenol
3-bromanylphenol

3-溴苯酚物理化学性质

[ 密度 ]:
1.7±0.1 g/cm3

[ 沸点 ]:
235.5±0.0 °C at 760 mmHg

[ 熔点 ]:
30 °C

[ 分子式 ]:
C₆H₅BrO

[ 分子量 ]:
173.007

[ 闪点 ]:
91.1±19.8 °C

[ 精确质量 ]:
171.952377

[ PSA ]:
20.23000

[ LogP ]:
2.63

[ 外观性状 ]:
白色至灰白色固体

[ 蒸汽压 ]:
0.0±0.4 mmHg at 25°C

[ 折射率 ]:
1.605

[ 储存条件 ]:
室温

[ 水溶解性 ]:
insoluble

3-溴苯酚MSDS

详细MSDS(安全技术说明书)

3-溴苯酚安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful;

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/39-S36/37/39

[ 危险品运输编码 ]:
2811

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
29081000

3-溴苯酚上下游产品

3-溴苯酚上游产品

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3-溴苯酚制备

由间氨基酚重氮化、溴代而得。将间氨基酚溶于硫酸，冷至10℃以下，滴加亚硝酸钠水溶液。重氮化反应后过滤，滤液用溴化亚铜水解。然后蒸馏，收集蒸出液加食盐后过滤，滤液用乙醚提取，提取液干燥，蒸馏回收乙醚，再蒸馏出间溴酚。

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3-溴苯酚海关

[ 海关编码 ]: 2908199090

[ 中文概述 ]:
HS:2908199090 其他酚及酚醇的仅含卤素取代基的衍生物及其盐增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

3-溴苯酚文献

Convenient QSAR model for predicting the complexation of structurally diverse compounds with β-cyclodextrins

Bioorg. Med. Chem. 17 , 896-904, (2009)

This paper reports a QSAR study for predicting the complexation of a large and heterogeneous variety of substances (233 organic compounds) with beta-cyclodextrins (beta-CDs). Several different theoret...

Cellular apoptosis and cytotoxicity of phenolic compounds: a quantitative structure-activity relationship study.

J. Med. Chem. 48 , 7234-42, (2005)

In this comprehensive study on the caspase-mediated apoptosis-inducing effect of 51 substituted phenols in a murine leukemia cell line (L1210), we determined the concentrations needed to induce caspas...

Pathways of formation of 2-, 3- and 4-bromophenol from bromobenzene. Proposed mechanism for C-S lyase reactions of cysteine conjugates.

Res. Commun. Chem. Pathol. Pharmacol. 80(3) , 259-82, (1993)

Bromobenzene is metabolized by the rat and guinea pig to 2-, 3- and 4-bromophenol. 3-Bromophenol is formed through the sulfur-series pathway to phenols. This route involves the enterohepatic circulati...

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