二氯硝基乙烷
二氯硝基乙烷名称
[ CAS 号 ]:
594-72-9
[ 中文名 ]:
二氯硝基乙烷
[ 英文名 ]:
1,1-dichloro-1-nitroethane
[中文别名 ]:
[英文别名 ]:
- Ethide
- 1,1-Dicloro-1-nitroetano
- Dichloro-1-nitroethane
- 1,1-Dichloro-1-nitroaethan
- Dichloronitroethane
- EINECS 209-854-0
- Caswell No. 313
- 1,1-Dichlor-1-nitroethan
- Ethane,1,1-dichloro-1-nitro
- 1,1-dichloro-1-nitro-ethane
二氯硝基乙烷物理化学性质
[ 密度 ]:
1.481 g/cm3
[ 沸点 ]:
123.5ºC at 760 mmHg
[ 分子式 ]:
C2H3Cl2NO2
[ 分子量 ]:
143.95700
[ 闪点 ]:
31.7ºC
[ 精确质量 ]:
142.95400
[ PSA ]:
45.82000
[ LogP ]:
1.93760
[ 外观性状 ]:
无色液体,带有辛辣气味
[ 折射率 ]:
1.467
[ 储存条件 ]:
库房通风低温干燥,与食品、氧化剂、酸类分开储运
二氯硝基乙烷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- KI1050000
- CHEMICAL NAME :
- Ethane, 1,1-dichloro-1-nitro-
- CAS REGISTRY NUMBER :
- 594-72-9
- BEILSTEIN REFERENCE NO. :
- 1751184
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 31
- MOLECULAR FORMULA :
- C2-H3-Cl2-N-O2
- MOLECULAR WEIGHT :
- 143.96
- WISWESSER LINE NOTATION :
- WNXGG1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 410 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 240 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 150 mg/kg
- TOXIC EFFECTS :
- Vascular - other changes Lungs, Thorax, or Respiration - acute pulmonary edema Gastrointestinal - ulceration or bleeding from stomach
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 580 mg/m3/6H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Behavioral - muscle weakness Lungs, Thorax, or Respiration - cough
- TYPE OF TEST :
- LCLo - Lowest published lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 580 mg/m3/6H
- TOXIC EFFECTS :
- Sense Organs and Special Senses (Eye) - lacrimation Behavioral - muscle weakness Lungs, Thorax, or Respiration - cough
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- REFERENCE :
- EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 21),2,1992 *** REVIEWS *** ACGIH TLV-TWA 12 mg/m3 (2 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD:air-CL 10 ppm (60 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,82,1971 OSHA PEL (Gen Indu):CL 10 ppm (60 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 10 ppm (60 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 10 ppm (60 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 10 ppm (60 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 ppm (10 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 10 ppm (60 mg/m3) JAN 1993 OEL-BELGIUM:TWA 2 ppm (12 mg/m3) JAN 1993 OEL-DENMARK:STEL 2 ppm (12 mg/m3) JAN 1993 OEL-FINLAND:TWA 10 ppm (60 mg/m3);STEL 20 ppm (120 mg/m3) JAN 1993 OEL-FRANCE:TWA 2 ppm (10 mg/m3) JAN 1993 OEL-GERMANY:TWA 10 ppm (60 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 2 ppm (10 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 10 ppm (60 mg/m3) JAN 1993 OEL-POLAND:TWA 30 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 ppm (12 mg/m3) JAN 1993 OEL-THAILAND:TWA 10 ppm (60 mg/m3) JAN 1993 OEL-TURKEY:TWA 10 ppm (60 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 1,1-DICHLORO-1-NITROETHANE-air:10H TWA 2 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992
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二氯硝基乙烷安全信息
[ 危害码 (欧洲) ]:
T
[ 风险声明 (欧洲) ]:
23/24/25
[ 安全声明 (欧洲) ]:
26-45
[ 危险品运输编码 ]:
UN 2650
[ 包装等级 ]:
II
[ 危险类别 ]:
6.1(a)
二氯硝基乙烷合成路线
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