2,3-二硝基甲苯

【用途一】
用于有机合成。

[ 密度 ]:
1.407 g/cm3

[ 沸点 ]:
331.5ºC at 760 mmHg

[ 熔点 ]:
59-61 °C(lit.)

[ 分子式 ]:
C₇H₆N₂O₄

[ 分子量 ]:
182.13400

[ 闪点 ]:
170.2ºC

[ 精确质量 ]:
182.03300

[ PSA ]:
91.64000

[ LogP ]:
2.85780

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

XT1400000

CHEMICAL NAME :

Toluene, 2,3-dinitro-

CAS REGISTRY NUMBER :

602-01-7

BEILSTEIN REFERENCE NO. :

2212428

LAST UPDATED :

199710

DATA ITEMS CITED :

12

MOLECULAR FORMULA :

C7-H6-N2-O4

MOLECULAR WEIGHT :

182.15

WISWESSER LINE NOTATION :

WNR B1 FNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

Standard Draize test

ROUTE OF EXPOSURE :

Administration onto the skin

SPECIES OBSERVED :

Rodent - rabbit

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - rat

DOSE/DURATION :

911 mg/kg

TOXIC EFFECTS :

Behavioral - somnolence (general depressed activity)

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Oral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

1072 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :

DNA damage

TEST SYSTEM :

Rodent - rat Liver

REFERENCE :

SinJF# Personal Communication from J.F. Sina, Merck Institute for Therapeutic Research, West Point, PA 19486, Oct. 26, 1982 Volume(issue)/page/year: 26OCT1982 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO 2,3-DINITROTOLUENE-air:10H CA TWA 1.5 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

[ 符号 ]:

GHS06, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311 + H331-H341-H350-H361f-H373-H410

[ 警示性声明 ]:
P201-P261-P273-P280-P301 + P310-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
R45

[ 安全声明 (欧洲) ]:
S53-S45-S60-S61

[ 危险品运输编码 ]:
UN 3454 6.1/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
XT1400000

[ 包装等级 ]:
II

[ 危险类别 ]:
6.1(a)

详细合成路线

2- 亚硝基 -3- 硝基甲苯和 65% 硝酸在 40-55 ℃ 反应 2.5h ，冷却，过滤，洗涤，干燥，即得 2,3- 二硝基甲

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