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(S)-缩水甘油

(S)-缩水甘油用途

用于合成多种手性医药中间体

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(S)-缩水甘油名称

[ CAS 号 ]:
60456-23-7

[ 中文名 ]:
(S)-缩水甘油

[ 英文名 ]:
(±)-Glycidol

[中文别名 ]:

[英文别名 ]:

(S)-(-)-2,3-epoxy-1-propanol
2-Oxiranylmethanol
(2S)-2-Oxiranylmethanol
(S)-(-)-2-(Hydroxymethyl)oxirane
2-Oxiranemethanol, (2S)-
(2S)-(-)-3-Hydroxy-1,2-propenoxide
MFCD00074874
(2S)-Oxiran-2-ylmethanol
(S)-(-)-Glycidol
[(2S)-oxiran-2-yl]methanol

(S)-缩水甘油物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
162.4±8.0 °C at 760 mmHg

[ 分子式 ]:
C₃H₆O₂

[ 分子量 ]:
74.078

[ 闪点 ]:
81.1±0.0 °C

[ 精确质量 ]:
74.036781

[ PSA ]:
32.76000

[ LogP ]:
-0.95

[ 外观性状 ]:
无色至淡黄色液体

[ 蒸汽压 ]:
0.7±0.7 mmHg at 25°C

[ 折射率 ]:
1.455

[ 储存条件 ]:
<0°C;存放于惰性气体之中;避免湿气 (分解),加热

[ 水溶解性 ]:
水溶性：完全混溶

(S)-缩水甘油MSDS

(S)-缩水甘油毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RR0508100

CHEMICAL NAME :: Oxiranemethanol, (S)-

CAS REGISTRY NUMBER :: 60456-23-7

BEILSTEIN REFERENCE NO. :: 0079783

LAST UPDATED :: 199612

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C3-H6-O2

MOLECULAR WEIGHT :: 74.09

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

TYPE OF TEST :: Sister chromatid exchange

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

DOSE/DURATION :: 2500 umol/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 278,289,1992

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(S)-缩水甘油安全信息

[ 符号 ]:

GHS05, GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H312-H315-H318-H331-H335-H350-H360

[ 警示性声明 ]:
P201-P261-P280-P305 + P351 + P338-P311

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R45;R60;R21/22;R23;R36/37/38;R68

[ 安全声明 (欧洲) ]:
S53-S45

[ 危险品运输编码 ]:
UN 2810

[ WGK德国 ]:
3

[ RTECS号 ]:
RR0508100

[ 危险类别 ]:
6.1

[ 海关编码 ]:
2910900090

(S)-缩水甘油合成路线

(S)-缩水甘油上下游产品

(S)-缩水甘油上游产品

(S)-缩水甘油下游产品

(S)-缩水甘油海关

[ 海关编码 ]: 2910900090

[ 中文概述 ]:
2910900090. 三节环环氧化物，环氧醇（酚，醚），包括其卤化，磺化，硝化或亚硝化的衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

(S)-缩水甘油文献

Direct Determination of MCPD Fatty Acid Esters and Glycidyl Fatty Acid Esters in Vegetable Oils by LC-TOFMS.

J. Am. Oil Chem. Soc. 88(1) , 1-14, (2011)

Analysis of MCPD esters and glycidyl esters in vegetable oils using the indirect method proposed by the DGF gave inconsistent results when salting out conditions were varied. Subsequent investigation ...

Cross metathesis as a general strategy for the synthesis of prostacyclin and prostaglandin analogues.

Org. Lett. 8 , 3101, (2006)

[reaction: see text] A cross metathesis (CM) approach has been successfully applied to introduce fully functionalized omega-side chain appendages of various prostacyclin and prostaglandin analogues, r...

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