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1,6-己二胺盐酸盐

1,6-己二胺盐酸盐名称

[ CAS 号 ]:
6055-52-3

[ 中文名 ]:
1,6-己二胺盐酸盐

[ 英文名 ]:
1,6-Hexanediamine dihydrochloride

[中文别名 ]:

[英文别名 ]:

hexane-1,6-diamine,dihydrochloride
1,6-Hexanediamine dihydrochloride
1,6-Hexanediamine, hydrochloride (1:2)
Hexane-1,6-diamine dihydrochloride
EINECS 227-977-8
MFCD00012528

1,6-己二胺盐酸盐物理化学性质

[ 沸点 ]:
205ºC at 760 mmHg

[ 熔点 ]:
256-257 °C(lit.)

[ 分子式 ]:
C₆H₁₈Cl₂N₂

[ 分子量 ]:
189.126

[ 闪点 ]:
81.1ºC

[ 精确质量 ]:
188.084702

[ PSA ]:
52.04000

[ LogP ]:
3.46880

[ 外观性状 ]:
近乎于白色结晶粉末

[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (吸湿)

[ 水溶解性 ]:
水溶性：完全溶解

1,6-己二胺盐酸盐MSDS

1,6-己二胺盐酸盐毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MO1312000

CHEMICAL NAME :: 1,6-Hexanediamine, dihydrochloride

CAS REGISTRY NUMBER :: 6055-52-3

LAST UPDATED :: 199712

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C6-H16-N2.2Cl-H

MOLECULAR WEIGHT :: 189.16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3682 mg/kg/2W-C

TOXIC EFFECTS :: Liver - changes in liver weight

REFERENCE :: NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No.206- Volume(issue)/page/year: NIH-93-3347

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 50 mg/m3/6H/13W-I

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes Blood - changes in leukocyte (WBC) count

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 800 mg/m3/6H/2W-I

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - other changes Related to Chronic Data - death

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 800 mg/m3/6H/2W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Endocrine - changes in thymus weight Related to Chronic Data - death

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 160 mg/m3/6H/13W-I

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - changes in lung weight Liver - changes in liver weight

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 20,348,1993

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1,6-己二胺盐酸盐安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
MO1312000

[ 海关编码 ]:
2921229000

1,6-己二胺盐酸盐合成路线

1,6-己二胺盐酸盐海关

[ 海关编码 ]: 2921229000

[ 中文概述 ]:
2921229000 六亚甲基二胺及其他盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921229000 hexamethylenediamine and its salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

1,6-己二胺盐酸盐文献

Immobilization of phenylalanine dehydrogenase and its application in flow-injection analysis system for determination of plasma phenylalanine.

Appl. Biochem. Biotechnol. 163(2) , 258-67, (2011)

Phenylalanine dehydrogenase (L-PheDH) from Sporosarcina ureae was immobilized on DEAE-cellulose, modified initially with 2-amino-4,6-dichloro-s-triazine followed by hexamethylenediamine and glutaralde...

Analysis of polyamines as carbamoyl derivatives in urine and serum by liquid chromatography-tandem mass spectrometry.

Biomed. Chromatogr. 22(1) , 73-80, (2008)

A quantitative analysis of polyamines in urine and serum by liquid chromatography-tandem mass spectrometry (LC-MS/MS) is described. The polyamines were carbamylated with isobutyl chloroformate, extrac...

Receptor-based detection of 2,4-dinitrotoluene using modified three-dimensionally ordered macroporous carbon electrodes.

ACS Appl. Mater. Interfaces 4(9) , 4731-9, (2012)

Detection of explosives, such as 2,4,6-trinitrotoluene (TNT), is becoming increasingly important. Here, 2,4-dinitrotoluene (DNT, a common analogue of TNT) is detected electrochemically. A receptor bas...

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