氟咯草酮

氟咯草酮用途

【用途一】
用于冬小麦、黑麦、棉花、马铃薯等作物苗前处理，防除阔叶杂草
【用途二】
吡咯烷酮类除草剂。胡萝卜素合成抑制剂。防除冬小麦和冬黑麦田繁缕、常春藤叶、婆婆纳和堇菜，棉花田反枝苋、马齿苋和龙葵，马铃薯田的猪殃殃、龙葵和波斯水苦菜，用500～700g有效成分/hm²芽前施药。在轻质土中生长的胡萝卜，用500g有效成分/hm²施药，并可增产。

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氟咯草酮名称

[ CAS 号 ]:
61213-25-0

[ 中文名 ]:
氟咯草酮

[ 英文名 ]:
Fluorochloridone

[中文别名 ]:

[英文别名 ]:

Flurochloridon
EINECS 262-661-3
MFCD00144317
Fluorochloridone
(3RS,4RS

氟咯草酮物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
453.7±45.0 °C at 760 mmHg

[ 熔点 ]:
80 - 81ºC

[ 分子式 ]:
C₁₂H₁₀Cl₂F₃NO

[ 分子量 ]:
312.115

[ 闪点 ]:
228.2±28.7 °C

[ 精确质量 ]:
311.009155

[ PSA ]:
20.31000

[ LogP ]:
2.47

[ 蒸汽压 ]:
0.0±1.1 mmHg at 25°C

[ 折射率 ]:
1.536

氟咯草酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UY5746500

CHEMICAL NAME :: 2-Pyrrolidinone, 3-chloro-4-(chloromethyl)-1-(3-(trifluoromethyl)pheny l)-

CAS REGISTRY NUMBER :: 61213-25-0

LAST UPDATED :: 199412

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C12-H10-Cl2-F3-N-O

MOLECULAR WEIGHT :: 312.13

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3650 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A825,1986

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10300 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,419,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A825,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >2150 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A825,1986

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氟咯草酮安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
26-27-36/37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ RTECS号 ]:
UY5746500

[ 海关编码 ]:
2933990016

氟咯草酮上下游产品

氟咯草酮上游产品

氟咯草酮下游产品

氟咯草酮制备

制备方法一
间三氟甲基苯胺经二氯代乙酰氯酰化，然后与3-溴代丙烯反应，生成物在氯化丁基三苯基鏻的存在下，于125℃反应17h，制得氟咯草酮。
制备方法二
合成N-烯丙基间三氟甲基苯胺，在烧瓶中加入0.1mol间三氟甲基苯胺，0.1mol三乙胺，50mL甲苯及适量催化剂加热升温至60℃，滴加0.1mol烯丙基氯，滴毕升温至85℃，反应数小时，反应液水洗、干燥，脱溶和未反应的间三氟甲基苯胺，得产品11.5g，含量93.4%，收率76.8%.
合成N-烯丙基-N-间三氟甲基苯基-2，2-二氯乙酰胺在烧瓶中加入0.05mol三乙胺，0.05mol N-烯丙基间三氟甲基苯胺及40mL二氯甲烷，滴加0.06mol二氯乙酰氯。滴毕，升温至60℃，保温反应1h，水洗，干燥，脱溶，得产品16.6g，含量88.8%，收率94.5%。
合成氟咯草酮在烧瓶中加入10g N-烯丙基N-间三氟甲基苯基-2，2-二氯乙酰胺，溶剂及催化剂，加热至回流。反应结束后，用稀酸中和、分层、干燥、减压脱溶，得产品氟咯草酮6.8g。

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氟咯草酮海关

[ 海关编码 ]: 2933990016

[ 中文概述 ]:
2933990016. 环菌唑,叶菌唑,灭菌唑,种菌唑等〔包括申嗪霉素,氟喹唑,哒螨灵,喹螨醚,氟草敏,氟咯草酮〕. 增值税率:17.0%. 退税率:9.0%. 监管条件:S(进出口农药登记证明). 最低关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2933990016 1-(2-(2,4-dichlorophenyl)pentyl)-1h-1,2,4-triazole。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

氟咯草酮文献

The physiological and biochemical effects of salicylic acid on sunflowers (Helianthus annuus) exposed to flurochloridone.

Ecotoxicol. Environ. Saf. 106 , 232-8, (2014)

In this study, we comparatively evaluated the effects of the flurochloridone as well as flurochloridone and exogenously applied salicylic acid (SA) on Helianthus annuus L. to find out herbicide-induce...

[Industrial hygiene in the use of the herbicide Raiser in cotton growing].

Gig. Tr. Prof. Zabol. (4) , 9-10, (1992)

Genotoxic and cytotoxic evaluation of the herbicide flurochloridone on Chinese hamster ovary (CHO-K1) cells.

Toxicol. In Vitro 26(1) , 157-63, (2012)

The in vitro effects of flurochloridone (FLC) and its formulations Twin Gold Pack® (25% a.i.) and Rainbow® (25% a.i.) were evaluated on Chinese hamster ovary (CHO-K1) cells by genotoxicity [sister chr...

更多文献

氟咯草酮

氟咯草酮用途

氟咯草酮名称

氟咯草酮物理化学性质

氟咯草酮毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

氟咯草酮安全信息

氟咯草酮上下游产品

氟咯草酮上游产品

氟咯草酮下游产品

氟咯草酮制备

氟咯草酮海关

氟咯草酮文献

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