1-甲基哌啶

【用途一】
用作药物和有机合成中间体
【用途二】
1-甲基哌啶是植物生长调节剂甲哌鎓的中间体。
【用途三】
药物和有机合成中间体。

[ 密度 ]:
0.817 g/mL at 20 °C(lit.)

[ 沸点 ]:
106-107 °C(lit.)

[ 熔点 ]:
-50 °C

[ 分子式 ]:
C₆H₁₃N

[ 分子量 ]:
99.17410

[ 闪点 ]:
38 °F

[ 精确质量 ]:
99.10480

[ PSA ]:
3.24000

[ LogP ]:
1.04000

[ 外观性状 ]:
无色透明液体

[ 折射率 ]:
n20/D 1.438

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 水溶解性 ]:
miscible

详细MSDS(安全技术说明书)

CHEMICAL IDENTIFICATION

RTECS NUMBER :

TN1225000

CHEMICAL NAME :

Piperidine, 1-methyl-

CAS REGISTRY NUMBER :

626-67-5

LAST UPDATED :

199710

DATA ITEMS CITED :

4

MOLECULAR FORMULA :

C6-H13-N

MOLECULAR WEIGHT :

99.20

WISWESSER LINE NOTATION :

T6NTJ A1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :

Intraperitoneal

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

400 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

BEXBAN Bulletin of Experimental Biology and Medicine (English Translation). Translation of BEBMAE. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) V.41- 1956- Volume(issue)/page/year: 86,1325,1978

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Subcutaneous

SPECIES OBSERVED :

Rodent - rabbit

DOSE/DURATION :

400 mg/kg

TOXIC EFFECTS :

Details of toxic effects not reported other than lethal dose value

REFERENCE :

BDCGAS Berichte der Deutschen Chemischen Gesellschaft. (Leipzig, Ger. Dem. Rep.) V.1-61, 1868-1928. For publisher information, see CHBEAM. Volume(issue)/page/year: 34,2408,1901

[ 符号 ]:

GHS02, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H314

[ 警示性声明 ]:
P210-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable;C:Corrosive;

[ 风险声明 (欧洲) ]:
R11;R20/22;R34

[ 安全声明 (欧洲) ]:
S7-S16-S26-S36/37/39-S45-S9-S33

[ 危险品运输编码 ]:
UN 3286 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TN1225000

[ 包装等级 ]:
II

[ 危险类别 ]:
3

[ 海关编码 ]:
29333999

详细合成路线

1-甲基哌啶上游产品

1-甲基哌啶下游产品

其制备方法是在反应釜中加入哌啶、甲醛，最后加甲酸，加热，保持温度90℃，反应6h，冷却，向混合物加入盐酸，升温加热蒸出过量甲醛和甲酸，残留物冷却，加入氢氧化钠，升温蒸出1-甲基哌啶和水混合物，此混合物经固体氢氧化钠干燥，放到蒸馏釜中蒸馏得产品。

[ 海关编码 ]: 29333999

Simultaneous determination of perfluorinated compounds and their potential precursors in mussel tissue and fish muscle tissue and liver samples by liquid chromatography-electrospray-tandem mass spectrometry.

J. Chromatogr. A. 1387 , 13-23, (2015)

An analytical method for the simultaneous determination in fish liver and muscle tissue and mussel samples of 14 perfluorinated compounds (PFCs), including three perfluoroalkylsulfonates (PFSAs), seve...

Self aggregation of supramolecules of nitroxides@cucurbit[8]uril revealed by EPR spectra.

Langmuir 25 , 13820-13832, (2009)

Supramolecular complexation behavior of cucurbiturils with paramagnetic nitroxide spin probes was examined by (1)H NMR, X-ray diffraction studies of crystals, computation, and EPR. Both cucurbit[7]uri...

Simultaneous determination of perfluoroalkyl phosphonates, carboxylates, and sulfonates in drinking water.

J. Chromatogr. A. 1218(37) , 6388-95, (2011)

A trace analytical method based on high performance liquid chromatography coupled to quadrupole time-of-flight high resolution mass spectrometry was developed for simultaneous determination of perfluo...

更多文献

公司名：上海化源世纪贸易有限公司

区域：上海市普陀区

价格：

联系人：徐经理

产品详情：1-甲基哌啶

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公司名：上海吉至生化科技有限公司

区域：上海市奉贤区

价格：
￥488.0/500ml ￥148.0/100ml

联系人：刘佳

产品详情：1-甲基哌啶

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公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥需询单/1mg ￥需询单/1mg ￥需询单/1mg ￥需询单/1mg

联系人：阿拉丁

产品详情：1-甲基哌啶

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