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氧化苯砷

氧化苯砷用途

【用途一】
用于有机合成。该品剧毒，用作杀虫剂。
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氧化苯砷名称

[ CAS 号 ]:
637-03-6

[ 中文名 ]:
氧化苯胂

[ 英文名 ]:
Arsine, oxophenyl-

[中文别名 ]:

[英文别名 ]:

氧化苯砷物理化学性质

[ 密度 ]:
1

[ 沸点 ]:
100ºC

[ 熔点 ]:
145-148 °C

[ 分子式 ]:
C6H5AsO

[ 分子量 ]:
168.025

[ 精确质量 ]:
167.955643

[ PSA ]:
17.07000

[ LogP ]:
0.47410

[ 外观性状 ]:
powder | white to yellow

[ 储存条件 ]:
Poison room

[ 稳定性 ]:
Stable.

[ 水溶解性 ]:
DMSO: 50 mg/mL

氧化苯砷MSDS

详细MSDS(安全技术说明书)

氧化苯砷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH8100000
CHEMICAL NAME :
Arsine, oxophenyl-
CAS REGISTRY NUMBER :
637-03-6
BEILSTEIN REFERENCE NO. :
2935227
LAST UPDATED :
199710
DATA ITEMS CITED :
12
MOLECULAR FORMULA :
C6-H5-As-O
MOLECULAR WEIGHT :
168.03
WISWESSER LINE NOTATION :
O-AS-R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1930 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 74,210,1942
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1570 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHBUA9 Pharmaceutical Bulletin. (Tokyo, Japan) V.1-5, 1953-57. For publisher information, see CPBTAL. Volume(issue)/page/year: 2,19,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1900 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 70,221,1940
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
790 ug/kg
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 69,342,1940 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1555 No. of Facilities: 191 (estimated) No. of Industries: 10 No. of Occupations: 16 No. of Employees: 5958 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1555 No. of Facilities: 606 (estimated) No. of Industries: 7 No. of Occupations: 6 No. of Employees: 1922 (estimated) No. of Female Employees: 695 (estimated)
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氧化苯砷安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H331-H410

[ 警示性声明 ]:
P261-P273-P301 + P310-P311-P501

[ 危害码 (欧洲) ]:
T:Toxic;N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R23/25;R50/53

[ 安全声明 (欧洲) ]:
S20/21-S28-S45-S60-S61

[ 危险品运输编码 ]:
UN 3465 6.1/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
CH8100000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1

氧化苯砷合成路线

详细合成路线

氧化苯砷制备

将苯砷酸、甲醇、浓盐酸按重量比1：5：2混合，加入少许碘化钾，然后通入二氧化硫至饱和。将反应生成的油状苯二氯砷用氢氧化钠溶液溶解，再用盐酸中和，使苯砷氧沉淀出来。
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氧化苯砷文献

Evolution of availability of curcumin inside poly-lactic-co-glycolic acid nanoparticles: impact on antioxidant and antinitrosant properties.

Int. J. Nanomedicine 10 , 5355-66, (2015)

Curcumin exhibits antioxidant properties potentially beneficial for human health; however, its use in clinical applications is limited by its poor solubility and relative instability. Nanoparticles ex...

Piperine inhibits the growth and motility of triple-negative breast cancer cells.

Cancer Lett. 357(1) , 129-40, (2014)

Piperine, an alkaloid from black pepper, is reported to have anticancer activities. In this study, we investigated the effect of piperine on the growth and motility of triple-negative breast cancer (T...

Differential regulation of GLUT1 activity in human corneal limbal epithelial cells and fibroblasts.

Biochimie 95(2) , 258-63, (2013)

The corneal epithelial tissue is a layer of rapidly growing cells that are highly glycolytic and express GLUT1 as the major glucose transporter. It has been shown that GLUT1 in L929 fibroblast cells a...


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推荐生产厂家/供应商：

公司名：上海阿拉丁生化科技股份有限公司

区域：上海市浦东新区

价格：
￥102.9/250mg ￥293.9/1g ￥需询单/1g ￥需询单/250g

联系人：阿拉丁李高志

产品详情：苯砷酰氧化物

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相关化合物

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