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柠檬烯环氧化物

柠檬烯环氧化物名称

[ CAS 号 ]:
6909-30-4

[ 中文名 ]:
(+)-反式-柠檬烯 1,2-环氧化物

[ 英文名 ]:
(+)-Trans-limonene1,2-epoxide

[中文别名 ]:

柠檬烯环氧化物

[英文别名 ]:

D-LIMONENE 1,2-EPOXIDE
(1S,2R,4R)-limonene 1,2-oxide
(1S,4R)-1,2-Epoxy-p-menth-8-ene
(1R,4S)-trans-limonene oxide
(4R)-limonene 1alpha,2alpha-epoxide
(+)-trans-Limonene oxide
(1S,2R,4R)-limonene-1,2-epoxide
(+)-trans-p-Mentha-1,8-diene 1,2-epoxide
(+)-trans-Limonene 1,2-epoxide
(1S,2R,4R)-trans-1,2-limonene epoxide

柠檬烯环氧化物物理化学性质

[ 密度 ]:
0.930 g/mL at 20ºC(lit.)

[ 分子式 ]:
C₁₀H₁₆O

[ 分子量 ]:
152.23300

[ 闪点 ]:
65ºC

[ 精确质量 ]:
152.12000

[ PSA ]:
12.53000

[ LogP ]:
2.52010

[ 外观性状 ]:
无色至浅黄色液体

[ 折射率 ]:
n20/D 1.466

[ 储存条件 ]:
2-8°C

柠檬烯环氧化物安全信息

[ 个人防护装备 ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2932999099

柠檬烯环氧化物上下游产品

柠檬烯环氧化物上游产品

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柠檬烯环氧化物海关

[ 海关编码 ]: 2932999099

[ 中文概述 ]:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

柠檬烯环氧化物文献

Catalytic mechanism of limonene epoxide hydrolase, a theoretical study.

J. Am. Chem. Soc. 127(41) , 14339-47, (2005)

The catalytic mechanism of limonene epoxide hydrolase (LEH) was investigated theoretically using the density functional theory method B3LYP. LEH is part of a novel limonene degradation pathway found i...

QM/MM study of the mechanism of enzymatic limonene 1,2-epoxide hydrolysis.

Biochim. Biophys. Acta 1824(2) , 263-8, (2012)

Limonene 1,2-epoxide hydrolase (LEH) is completely different from those of classic epoxide hydrolases (EHs) which catalyze the hydrolysis of epoxides to vicinal diols. A novel concerted general acid c...

Total synthesis of (+)-cymbodiacetal: a re-evaluation of the biomimetic route.

J. Org. Chem. 75(24) , 8465-70, (2010)

A total synthesis of (+)-cymbodiacetal (1) has been completed from (R)-(+)-limonene oxide using a hetero-Diels-Alder cycloaddition as a key step. The key Diels-Alder cycloaddition proceeds with endo-s...

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