3,3-二甲基氧杂环丁烷
3,3-二甲基氧杂环丁烷名称
[ CAS 号 ]:
6921-35-3
[ 中文名 ]:
3,3-二甲基氧杂环丁烷
[ 英文名 ]:
3,3-Dimethyloxetane
[中文别名 ]:
[英文别名 ]:
- 3,3-dimethyloxetane
- MFCD00005168
3,3-二甲基氧杂环丁烷物理化学性质
[ 密度 ]:
0.835
[ 沸点 ]:
81ºC
[ 分子式 ]:
C5H10O
[ 分子量 ]:
86.13230
[ 闪点 ]:
-9ºC
[ 精确质量 ]:
86.07320
[ PSA ]:
9.23000
[ LogP ]:
1.04280
[ 折射率 ]:
1.399
[ 储存条件 ]:
室温
3,3-二甲基氧杂环丁烷MSDS
3,3-二甲基氧杂环丁烷毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- TZ3150000
- CHEMICAL NAME :
- Propane, 1,3-epoxy-2,2-dimethyl-
- CAS REGISTRY NUMBER :
- 6921-35-3
- BEILSTEIN REFERENCE NO. :
- 0102430
- LAST UPDATED :
- 199612
- DATA ITEMS CITED :
- 3
- MOLECULAR FORMULA :
- C5-H10-O
- MOLECULAR WEIGHT :
- 86.15
- WISWESSER LINE NOTATION :
- T4OTJ C1 C1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Behavioral - general anesthetic
- REFERENCE :
- JMPCAS Journal of Medicinal and Pharmaceutical Chemistry. (Washington, DC) V.1-5, 1959-62. For publisher information, see JMCMAR. Volume(issue)/page/year: 1,355,1959 ** TUMORIGENIC DATA **
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1020 mg/kg/61W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- REFERENCE :
- BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 17,100,1963 *** REVIEWS *** TOXICOLOGY REVIEW 22HAAD "Microbial Toxins, 1970-72," Ajil, S.J., et al., eds., New York, Academic Press, Inc., 1970-72 Volume(issue)/page/year: 6,409,1971
3,3-二甲基氧杂环丁烷安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H225-H302 + H312 + H332
[ 警示性声明 ]:
P210-P280
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ 危害码 (欧洲) ]:
Xn;F
[ 风险声明 (欧洲) ]:
R11;R20/21/22
[ 安全声明 (欧洲) ]:
16-36/37/39-45
[ 危险品运输编码 ]:
UN 1993
[ RTECS号 ]:
TZ3150000
[ 包装等级 ]:
II
[ 海关编码 ]:
2932999099
3,3-二甲基氧杂环丁烷合成路线
3,3-二甲基氧杂环丁烷上下游产品
3,3-二甲基氧杂环丁烷上游产品
3,3-二甲基氧杂环丁烷下游产品
3,3-二甲基氧杂环丁烷海关
[ 海关编码 ]: 2932999099
[ 中文概述 ]:
2932999099. 其他仅含氧杂原子的杂环化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:20.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
3,3-二甲基氧杂环丁烷文献
Makromol. Chem. 179(7) , 1681-88, (1978)
Copolymerization of oxetane with 3, 3-dimethyloxetane-I. Reactivity parameters and microstructure of the copolymers. Bucquoye M and Goethals EJ.
Eur. Polymer J. 14(5) , 323-28, (1978)
Mild one-step synthesis of dibromo compounds from cyclic ethers.
J. Org. Chem. 77(24) , 11227-31, (2012)
A novel one-step method for mildly converting cyclic ethers into dibromo compounds is reported. Alcohols, oximes, aldehydes, and ketones are known to react under Appel or Corey-Fuchs reaction conditio...
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