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3-甲氨基丙腈

3-甲氨基丙腈用途

【用途一】
用于有机合成。

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3-甲氨基丙腈名称

[ CAS 号 ]:
693-05-0

[ 中文名 ]:
3-甲胺基丙腈

[ 英文名 ]:
3-(Methylamino)propanenitrile

[中文别名 ]:

[英文别名 ]:

MFCD00001954
Propanenitrile, 3-(methylamino)-
3-(Methylamino)propanenitrile
Propanenitrile, 3- (methylamino)-
EINECS 211-740-0
β-(Methylamino)propionitrile
3-Methyl aminopropionitrile

3-甲氨基丙腈物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
180.7±23.0 °C at 760 mmHg

[ 熔点 ]:
-21ºC

[ 分子式 ]:
C₄H₈N₂

[ 分子量 ]:
84.120

[ 闪点 ]:
63.1±22.6 °C

[ 精确质量 ]:
84.068748

[ PSA ]:
35.82000

[ LogP ]:
-0.79

[ 外观性状 ]:
透明黄色液体

[ 蒸汽压 ]:
0.9±0.3 mmHg at 25°C

[ 折射率 ]:
1.412

[ 储存条件 ]:
室温

3-甲氨基丙腈MSDS

详细MSDS(安全技术说明书)

3-甲氨基丙腈毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TZ4910000

CHEMICAL NAME :: Propanenitrile, 3-(methylamino)-

CAS REGISTRY NUMBER :: 693-05-0

BEILSTEIN REFERENCE NO. :: 1699160

LAST UPDATED :: 199710

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C4-H8-N2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2260 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Kidney, Ureter, Bladder - hematuria

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2260 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - tremor Skin and Appendages - hair

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570990

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1400 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ZAARAM Zentralblatt fuer Arbeitsmedizin und Arbeitsschutz. (Darmstadt, Fed. Rep. Ger.) V.1-25, 1951-75. Volume(issue)/page/year: 19,225,1969 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4 gm/kg/5D-I

TOXIC EFFECTS :: Behavioral - food intake (animal) Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570990

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3-甲氨基丙腈安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H312-H315-H319-H332-H335

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
TZ4910000

[ 海关编码 ]:
29269095

3-甲氨基丙腈合成路线

详细合成路线

3-甲氨基丙腈上下游产品

3-甲氨基丙腈上游产品

3-甲氨基丙腈下游产品

3-甲氨基丙腈制备

由丙烯腈与甲胺经加成而得。将甲胺-乙醇溶液加入反应锅内，搅拌冷却至5℃，滴加丙烯腈-乙醇溶液，保持10-20℃，约3h加完。在15℃以下继续反应1h后，常压蒸去乙醇，再减压蒸馏，收集112-115（13.3kPa）馏分，即分3-甲氨基丙腈。

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3-甲氨基丙腈海关

[ 海关编码 ]: 2926909090

[ 中文概述 ]:
2926909090 其他腈基化合物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2926909090 other nitrile-function compounds VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

3-甲氨基丙腈

3-甲氨基丙腈用途

3-甲氨基丙腈名称

3-甲氨基丙腈物理化学性质

3-甲氨基丙腈MSDS

详细MSDS(安全技术说明书)

3-甲氨基丙腈毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

3-甲氨基丙腈安全信息

3-甲氨基丙腈合成路线

详细合成路线

3-甲氨基丙腈上下游产品

3-甲氨基丙腈上游产品

3-甲氨基丙腈下游产品

3-甲氨基丙腈制备

3-甲氨基丙腈海关

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