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[1,1'-双(二苯基膦基)二茂铁]二氯化钯

[1,1'-双(二苯基膦基)二茂铁]二氯化钯用途

【用途1】
催化剂，用于羰基化反应，交叉耦合反应，铃木反应。

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[1,1'-双(二苯基膦基)二茂铁]二氯化钯名称

[ CAS 号 ]:
72287-26-4

[ 中文名 ]:
[1,1'-双(二苯基膦基)二茂铁]二氯化钯

[ 英文名 ]:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[中文别名 ]:

[英文别名 ]:

MFCD00015757
(dppf)2PdCl2
(II)dichloromethane adduct
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropall
PDCL2(DPPF)
EINECS 460-040-3

[1,1'-双(二苯基膦基)二茂铁]二氯化钯物理化学性质

[ 熔点 ]:
275-280ºC

[ 分子式 ]:
C₃₄H₂₈Cl₂FeP₂Pd

[ 分子量 ]:
731.705

[ 精确质量 ]:
729.942749

[ PSA ]:
27.18000

[ LogP ]:
7.76790

[ 储存条件 ]:
室温

[ 水溶解性 ]:
Soluble in dichloromethane.

[1,1'-双(二苯基膦基)二茂铁]二氯化钯MSDS

详细MSDS(安全技术说明书)

[1,1'-双(二苯基膦基)二茂铁]二氯化钯安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R20/21/22

[ 安全声明 (欧洲) ]:
S36/37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
28439000

[1,1'-双(二苯基膦基)二茂铁]二氯化钯上下游产品

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[1,1'-双(二苯基膦基)二茂铁]二氯化钯文献

Suzuki-Miyaura coupling of NHC-boranes: a new addition to the C-C coupling toolbox.

Org. Lett. 11 , 4914, (2009)

Complexes of triaryl- and trialkylboranes with N-heterocyclic carbenes (NHCs) participate in Suzuki-Miyaura cross-coupling reactions and provide coupled products in good yields under base-free conditi...

A Pd(II)-catalyzed ring-expansion reaction of cyclic 2-azidoalcohol derivatives: synthesis of azaheterocycles.

J. Am. Chem. Soc. 131 , 12886, (2009)

A Pd(II)-catalyzed ring expansion-reaction of cyclic 2-azidoalcohol derivatives was found to proceed via an unprecedented C-C bond cleavage-C-N bond formation sequence, providing substituted azahetero...

Electrophilic activation of benzaldehydes through ortho palladation: one-pot synthesis of 3-methylene-indan-1-ols through a domino allylstannylation/Heck reaction under neutral conditions.

Angew. Chem. Int. Ed. Engl. 48 , 6148, (2009)

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