钡
钡用途
广泛用于合金,有铅、钙、镁、钠、锂、铝及镍等合金。用于清除无线电真空管中残留的微量气体。
【用途二】
用于制钡盐、合金、焰火、核反应堆等,也是精炼铜时的优良除氧剂。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置;评价方法;工作标准;质量保证/质量控制;其他。
【用途三】
用于制钡盐、合金、焰火等;也是精制炼铜时的优良去氧剂。 钡是一种金属元素,银白色,燃烧时发黄绿色火焰。钡的盐类用做高级白色颜料。金属钡是铜精炼时的优良去氧剂:~餐(诊断某些食管、胃肠道疾患的检查方法,病人服硫酸钡后,用X射线透视或拍片)。 钡、锶、钙和镁同是碱土金属,也是地壳中含量较多的元素。不过钡和锶在地壳中的含量与钙、镁相比,还是较少的。再加上它们的化合物的实际应用不及钙和镁的化合物广泛。因此它们的化合物比钙和镁的化合物晚些被人们认识,只是戴维把钡和锶和钙、镁同时从化合物中电解分离出来。
钡名称
[ CAS 号 ]:
7440-39-3
[ 中文名 ]:
钡
[ 英文名 ]:
barium
[中文别名 ]:
[英文别名 ]:
- EINECS 231-149-1
- Barium
- MFCD00134031
- barium powder
- baryum
- barium strontium-containing oxide
- bario
- UNII-24GP945V5T
钡物理化学性质
[ 密度 ]:
3.6 g/mL at 25 °C(lit.)
[ 沸点 ]:
1640 °C(lit.)
[ 熔点 ]:
725 °C(lit.)
[ 分子式 ]:
Ba
[ 分子量 ]:
137.32700
[ 精确质量 ]:
137.90500
[ 外观性状 ]:
rod
[ 储存条件 ]:
库房通风低温干燥,与酸、氧化剂、卤代烃分开存放
[ 稳定性 ]:
Stability Reacts vigorously or violently with acids, water, tetrachloromethane, small halogenated hydrocarbons. Should be stored under an inert material such as petroleum ether to exclude air. Flammable.
钡MSDS
钡毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- CQ8370000
- CHEMICAL NAME :
- Barium
- CAS REGISTRY NUMBER :
- 7440-39-3
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 32
- MOLECULAR FORMULA :
- Ba
- MOLECULAR WEIGHT :
- 137.34
- WISWESSER LINE NOTATION :
- .BA
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 26622 mg/kg/69W-C
- REFERENCE :
- JTEHD6 Journal of Toxicology and Environmental Health. (Hemisphere Pub., 1025 Vermont Ave., NW, Washington, DC 20005) V.1- 1975/76- Volume(issue)/page/year: 28,373,1989 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 0.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,21,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Ba)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.5 mg/m3 JAN 1993 OEL-AUSTRIA:TWA 0.5 mg/m3 JAN 1993 OEL-BELGIUM:TWA 0.5 mg/m3 JAN 1993 OEL-DENMARK:TWA 0.5 mg/m3 JAN 1993 OEL-FINLAND:TWA 0.5 mg/m3 JAN 1993 OEL-GERMANY:TWA 0.5 mg/m3 (total dust) JAN 1993 OEL-HUNGARY:STEL 0.5 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.5 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.5 mg/m3 JAN 1993 OEL-POLAND:TWA 0.5 mg/m3;STEL 1.5 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.5 mg/m3;STEL 1 mg/m3 JAN 1993 OEL-TURKEY:TWA 0.5 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.5 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO BARIUM, soluble compounds-air:10H TWA 0.5 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 08625 No. of Facilities: 657 (estimated) No. of Industries: 13 No. of Occupations: 31 No. of Employees: 6101 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 08625 No. of Facilities: 901 (estimated) No. of Industries: 15 No. of Occupations: 64 No. of Employees: 10394 (estimated) No. of Female Employees: 3598 (estimated)
钡安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H261-H315-H319-H335
[ 警示性声明 ]:
P231 + P232-P305 + P351 + P338-P335 + P334-P370 + P378-P402 + P404
[ 个人防护装备 ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
C,Xi,F
[ 风险声明 (欧洲) ]:
R25
[ 安全声明 (欧洲) ]:
S23-S26-S36-S36/37/39-S45-S43-S36/37-S16
[ 危险品运输编码 ]:
UN 3264 8/PG 3
[ WGK德国 ]:
3
[ RTECS号 ]:
CQ8370000
[ 包装等级 ]:
III
[ 危险类别 ]:
8
钡合成路线
钡上下游产品
钡上游产品
钡下游产品
钡制备
1.铝热还原法:将硝酸钡热分解制得氧化钡,用细粒铝作还原剂,配料比按3BaO:2Al进行,把氧化钡和铝先制成团矿,将此团矿装入蒸馏器,加热至1150℃进行还原蒸馏,制得钡纯度为99%。
2.钡与钙锶相似,也可用铝热还原法制备。氧化钡由硝酸钡热分解得到。制造料坯按BaO∶Al=3∶2(摩尔比)配料,还原装置与操作步骤与锶、钙、镁的热还原法相同。冷凝器温度为500~700℃,还原温度1150℃。加热5小时得到的产品纯度可达97%~98%。取出钡时很容易着火。最保险的是在甲苯下进行此操作。钡的蒸馏纯制方法也与镁、钙相同。在1050℃下,40克粗制钡4小时蒸馏完毕,蒸馏三次之后纯度可达到99.6%。
钡文献
J. Neurosci. 34(35) , 11769-80, (2014)
Hippocampal oscillations are critical for information processing, and are strongly influenced by inputs from the medial septum. Hippocamposeptal neurons provide direct inhibitory feedback from the hip...
Trichloroethylene and trichloroethanol-induced formic aciduria and renal injury in male F-344 rats following 12 weeks exposure.Toxicology 323 , 70-7, (2014)
Trichloroethylene (TCE) is widely used as a cleaning and decreasing agent and has been shown to cause liver tumours in rodents and a small incidence of renal tubule tumours in male rats. The basis for...
Safety and efficacy of ethylenediaminetetraacetic acid for removing microcapsules.J. Surg. Res. 183(1) , 442-9, (2013)
Microencapsulated islets are used to prevent immune rejection associated with pancreatic islet transplantation, but cellular overgrowth affects transplantation success, necessitating removal of microc...
相关化工产品/化学物质:
推荐生产厂家/供应商:
公司名:上海化源世纪贸易有限公司
区域:上海市普陀区
价格:
联系人:徐经理
产品详情:钡棒
公司名:上海阿拉丁生化科技股份有限公司
区域:上海市浦东新区
价格:
¥需询单/1mg
¥需询单/1g
¥需询单/1g
¥需询单/1g
联系人:阿拉丁
产品详情:钡标准溶液
公司名:广东翁江化学试剂有限公司
区域:韶关市翁源县
价格:
¥320.0/100ml
¥160.0/100ml
¥160.0/50ml
联系人:朱丽丹
产品详情:钡标准溶液
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相关化合物
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