Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

名称

[ CAS 号 ]:
761459-93-2

[ 英文名 ]:
Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

物理化学性质

[ 熔点 ]:
162-221°C

[ 分子式 ]:
C20H19ClPdSe2

[ 分子量 ]:
559.18

[ 储存条件 ]:
2-8°C

安全信息

[ 符号 ]:

GHS06, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301 + H311 + H331-H351

[ 警示性声明 ]:
P261-P280-P301 + P310-P311

[ 危害码 (欧洲) ]:
T

[ 风险声明 (欧洲) ]:
23/24/25-40

[ 安全声明 (欧洲) ]:
36/37-45

[ 危险品运输编码 ]:
UN 3283 6.1 / PGIII

[ WGK德国 ]:
3

文献

Petasis Borono-Mannich reaction and allylation of carbonyl compounds via transient allyl boronates generated by palladium-catalyzed substitution of allyl alcohols. an efficient one-pot route to stereodefined alpha-amino acids and homoallyl alcohols.

J. Am. Chem. Soc. 129 , 13723 - 13731, (2007)

An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketone...


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