赤霉素
赤霉素用途
赤霉素名称
[ CAS 号 ]:
77-06-5
[ 中文名 ]:
赤霉酸
[ 英文名 ]:
Gibberellins
[中文别名 ]:
[英文别名 ]:
- Ralex
- Activol
- Maxon
- Gibbrel
- ryzup
- Gibberellin X
- Gibberelic acid
- GIBREL
- GA3
- GIBBEX
赤霉素生物活性
赤霉素物理化学性质
[ 密度 ]:
1.5±0.1 g/cm3
[ 沸点 ]:
628.6±55.0 °C at 760 mmHg
[ 熔点 ]:
227 °C
[ 分子式 ]:
C19H22O6
[ 分子量 ]:
346.374
[ 闪点 ]:
231.4±25.0 °C
[ 精确质量 ]:
346.141632
[ PSA ]:
104.06000
[ LogP ]:
0.01
[ 外观性状 ]:
白色结晶粉末
[ 蒸汽压 ]:
0.0±4.2 mmHg at 25°C
[ 折射率 ]:
1.661
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
[ 稳定性 ]:
Stable. Combustible. Incompatible with acids, strong oxidizing agents.
[ 水溶解性 ]:
5 G/L (20 º C)
赤霉素MSDS
赤霉素毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- LY8990000
- CHEMICAL NAME :
- Gibberellic acid
- CAS REGISTRY NUMBER :
- 77-06-5
- BEILSTEIN REFERENCE NO. :
- 0054346
- LAST UPDATED :
- 199706
- DATA ITEMS CITED :
- 13
- MOLECULAR FORMULA :
- C19-H22-O6
- MOLECULAR WEIGHT :
- 346.41
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 6300 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 8500 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 142 gm/kg/78W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Lungs, Thorax, or Respiration - tumors Liver - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Amphibian - toad
- DOSE/DURATION :
- 13200 mg/kg/22W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Liver - tumors
MUTATION DATA
- TYPE OF TEST :
- DNA damage
- TEST SYSTEM :
- Mammal - species unspecified Lymphocyte
- DOSE/DURATION :
- 1 mmol/L
- REFERENCE :
- PYTCAS Phytochemistry. An International Journal of Plant Biochemistry. (Pergamon Press Inc., Maxwell House, Fairview Park, Elmsford, NY 10523) V.1- 1961- Volume(issue)/page/year: 11,3135,1972 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83979 No. of Facilities: 33 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 297 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83979 No. of Facilities: 10 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 249 (estimated) No. of Female Employees: 144 (estimated)
赤霉素安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H319
[ 警示性声明 ]:
P305 + P351 + P338
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xi:Irritant
[ 风险声明 (欧洲) ]:
R36
[ 安全声明 (欧洲) ]:
26-36
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
3
[ RTECS号 ]:
LY8990000
[ 危险类别 ]:
5.2
[ 海关编码 ]:
29322980
赤霉素上下游产品
赤霉素上游产品
赤霉素下游产品
赤霉素制备
1.由gibberella fujikuroi菌种培养液通入无菌空气发酵后提炼精制而得。接种量为最终发酵罐液的4%,在温度为25~30℃下,不断搅拌和通风,搅拌过程中,用十八碳醇做抗沫剂。发酵完毕后,溶液用氢氧化钡沉淀并过滤。然后在阳离子交换树脂上,在pH=50时吸附并用NH3或其他碱性缓冲液洗脱,再进行精制处理而得。
2.赤霉素可用发酵方法生产。利用赤霉菌在麸皮、蔗糖和无机盐等培养基中进行发酵,赤霉菌代谢产生赤霉素,发酵液经溶媒提取、浓缩即得。
3.现都采用发酵法制取。发酵液经过离子交换树脂 Amberlite XAD-4柱,水洗至干净后,以90%丙酮的水溶液洗脱,收集洗脱液并且浓缩干燥,成品中赤霉酸含量90%以上。
赤霉素海关
[ 海关编码 ]: 29322980
赤霉素文献
Plant Physiol. 166(4) , 2179-94, (2014)
Plants have evolved an elaborate signaling network to ensure an appropriate level of immune response to meet the differing demands of developmental processes. Previous research has demonstrated that D...
Gibberellin Promotes Shoot Branching in the Perennial Woody Plant Jatropha curcas.Plant Cell Physiol. 56 , 1655-66, (2015)
Strigolactone (SL), auxin and cytokinin (CK) interact to regulate shoot branching. CK has long been considered to be the only key phytohormone to promote lateral bud outgrowth. Here we report that gib...
SCARECROW-LIKE15 interacts with HISTONE DEACETYLASE19 and is essential for repressing the seed maturation programme.Nat. Commun. 6 , 7243, (2015)
Epigenetic regulation of gene expression is critical for controlling embryonic properties during the embryo-to-seedling phase transition. Here we report that a histone deacetylase19 (HDA19)-associated...
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产品详情:赤霉素GA3
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产品详情:Gibberellic Acid
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¥30.9/100mg
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¥916.9/100mg
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相关化合物
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