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1,1-二氯丙烷

1,1-二氯丙烷名称

[ CAS 号 ]:
78-99-9

[ 中文名 ]:
1,1-二氯丙烷

[ 英文名 ]:
1,1-dichloropropane

[英文别名 ]:

Propylidene dichloride
1,1-dichloro-propan
dichloro-1,1propane
dichloropropane
1,1-dichloro-propane
propane,1,1-dichloro
MFCD00074845
EINECS 201-165-3
r270fb
PROPYLIDENE CHLORIDE

1,1-二氯丙烷物理化学性质

[ 密度 ]:
1.13 g/mL at 25ºC(lit.)

[ 沸点 ]:
88ºC(lit.)

[ 熔点 ]:
-83.56°C (estimate)

[ 分子式 ]:
C₃H₆Cl₂

[ 分子量 ]:
112.98600

[ 闪点 ]:
45 °F

[ 精确质量 ]:
111.98500

[ LogP ]:
2.20010

[ 外观性状 ]:
无色澄清液体

[ 折射率 ]:
n20/D 1.4275(lit.)

[ 储存条件 ]:
室温

[ 水溶解性 ]:
organic solvents: soluble(lit.)

1,1-二氯丙烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: TX9450000

CHEMICAL NAME :: Propane, 1,1-dichloro-

CAS REGISTRY NUMBER :: 78-99-9

BEILSTEIN REFERENCE NO. :: 1731152

LAST UPDATED :: 199806

DATA ITEMS CITED :: 6

MOLECULAR FORMULA :: C3-H6-Cl2

MOLECULAR WEIGHT :: 112.99

WISWESSER LINE NOTATION :: GYG2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,98,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4000 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 14 mL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

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1,1-二氯丙烷安全信息

[ 符号 ]:

GHS02, GHS07, GHS08

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H315-H319-H332-H335-H351

[ 警示性声明 ]:
P210-P261-P281-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F,Xn

[ 风险声明 (欧洲) ]:
20/21/22-36/37/38-40-11

[ 安全声明 (欧洲) ]:
S16;S26;S45;S36/S37/S39

[ 危险品运输编码 ]:
UN 1993 3/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
TX9450000

[ 包装等级 ]:
II

[ 危险类别 ]:
3.1

1,1-二氯丙烷合成路线

详细合成路线

1,1-二氯丙烷文献

Flash vacuum pyrolysis over magnesium. Part 1. Pyrolysis of benzylic, other aryl/alkyl and aliphatic halides.

J. Chem. Soc. Perkin Trans. I 3 , 402-415, (2002)

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