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N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺名称

[ CAS 号 ]:
782495-18-5

[ 中文名 ]:
N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺

[ 英文名 ]:
(S)-1,1,1-TRIFLUORO-N-(PYRROLIDIN-2-YLMETHYL)METHANESULFONAMIDE

[中文别名 ]:

N-[(2s)-2-吡咯烷甲基]-三氟甲烷磺酰胺

[英文别名 ]:

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺物理化学性质

[ 熔点 ]:
205-215°C

[ 分子式 ]:
C₆H₁₁F₃N₂O₂S

[ 分子量 ]:
232.22400

[ 精确质量 ]:
232.04900

[ PSA ]:
66.58000

[ LogP ]:
1.97810

[ 储存条件 ]:
2-8°C

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺MSDS

详细MSDS(安全技术说明书)

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺安全信息

[ 符号 ]:

GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C: Corrosive;

[ 风险声明 (欧洲) ]:
34

[ 安全声明 (欧洲) ]:
26-36/37/39-45

[ 危险品运输编码 ]:
UN 3263 8/PG 3

[ 危险类别 ]:
8.0

[ 海关编码 ]:
2935009090

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺海关

[ 海关编码 ]: 2935009090

[ 中文概述 ]:
2935009090 其他磺（酰）胺. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:35.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2935009090 other sulphonamides VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:35.0%

N-[(2S)-2-吡咯烷甲基]-三氟甲磺酰胺文献

A recyclable fluorous (S)-pyrrolidine sulfonamide promoted direct, highly enantioselective Michael addition of ketones and aldehydes to nitroolefins in water.

Org. Lett. 8 , 3077-3079, (2006)

[reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ke...

Highly enantioselective aldol reactions catalyzed by a recyclable fluorous (S) pyrrolidine sulfonamide on water.

Org. Lett. 10 , 1211-1214, (2008)

Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the org...

Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.

Angew. Chem. Int. Ed. Engl. 44 , 1369-1371, (2005)

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