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噻吩磺隆

噻吩磺隆用途

Thifensulfuron-methyl 是一种磺酰脲类除草剂,主要用于防治小麦,玉米和大豆田中的阔叶杂草。
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噻吩磺隆名称

[ CAS 号 ]:
79277-27-3

[ 中文名 ]:
噻吩磺隆

[ 英文名 ]:
Thifensulfuron-methyl

[中文别名 ]:

[英文别名 ]:

噻吩磺隆生物活性

[ 描述 ]:

Thifensulfuron-methyl 是一种磺酰脲类除草剂,主要用于防治小麦,玉米和大豆田中的阔叶杂草。

[ 相关类别 ]:

研究领域 >> 其他
信号通路 >> 其他 >> 其他

[参考文献]

[1]. Weisong Zhao, et al. Biodegradation of thifensulfuron-methyl by Ochrobactrum sp. in liquid medium and soil. Biotechnol Lett. 2015 Jul;37(7):1385-92.

噻吩磺隆物理化学性质

[ 密度 ]:
1.56 g/cm3

[ 熔点 ]:
176°C

[ 分子式 ]:
C12H13N5O6S2

[ 分子量 ]:
387.39200

[ 精确质量 ]:
387.03100

[ PSA ]:
186.09000

[ LogP ]:
2.09180

[ 外观性状 ]:
白色晶体

[ 折射率 ]:
1.608

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

噻吩磺隆MSDS

详细MSDS(安全技术说明书)

噻吩磺隆毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XM8463000
CHEMICAL NAME :
2-Thiophenecarboxylic acid, 3-(((((4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino)ca rbonyl)amino)sulfonyl )-, methyl ester
CAS REGISTRY NUMBER :
79277-27-3
LAST UPDATED :
199701
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C12-H13-N5-O6-S2
MOLECULAR WEIGHT :
387.42

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C239,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>7900 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 18,S219,1993
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 18,S219,1993
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C239,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>2510 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,814,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
40950 mg/kg/13W-C
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Nutritional and Gross Metabolic - weight loss or decreased weight gain Biochemical - Metabolism (Intermediary) - other proteins
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 18,S219,1993
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
110 gm/kg/2Y-C
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 18,S219,1993
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
68438 mg/kg/1Y-C
TOXIC EFFECTS :
Behavioral - food intake (animal) Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
NNGADV Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170, Japan) V.1- 1976- Volume(issue)/page/year: 18,S219,1993
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噻吩磺隆安全信息

[ 符号 ]:

GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H410

[ 警示性声明 ]:
P273-P391-P501

[ 个人防护装备 ]:
Eyeshields;Gloves

[ 危害码 (欧洲) ]:
N:Dangerousfortheenvironment;

[ 风险声明 (欧洲) ]:
R50/53

[ 安全声明 (欧洲) ]:
S60-S61

[ 危险品运输编码 ]:
UN3077 9/PG 3

[ RTECS号 ]:
XM8463000

噻吩磺隆上下游产品

噻吩磺隆上游产品

噻吩磺隆下游产品

噻吩磺隆制备

3-氨基-2-羧甲基噻吩的制备 丙烯腈在DMF存在下，于10～12℃通氯反应6～7h，得2，3-二氯丙腈；巯基乙酸在浓硫酸存在下，与无水甲醇于室温下反应8h，得巯基乙酸甲酯。
将巯基乙酸甲酯、无水甲醇和甲醇钠冷至10～15℃，滴加二氯丙腈和无水甲醇溶液，滴毕于10～15℃继续反应5h，减压蒸出甲醇，残余物冷却后加入冰水，过滤，产品收率55%，m.p. 58～61℃。
2-羟甲基-3-磺酰氯噻吩的制备 将冰醋酸及少许盐酸在泠却下通入二氧化硫，置冰浴中待用。
将3-氨基-2-羧甲基噻吩于0～5℃加入到盐酸、冰醋酸混合液中，搅拌，将亚硝酸钠水溶液慢慢滴入，继续反应30min，于0℃将待用的二氧化硫溶液加入，再加少许氯化亚铜，控制温度自然升至25～30℃，反应10h，将反应液倒入冰水中，过滤、洗涤、干燥，收率75.7%，m.p.66～68℃。
2-羧甲基-3-磺酰氨基噻吩的制备 以二氯乙烷为溶剂，将所得的磺酰氯噻吩溶解，冷却至5℃，通入氨气。氨解产物过滤，滤液浓缩处理得产品，收率95%，m.p. 110～114℃。
噻磺隆的合成 将2-羧甲基-3-磺酰氨基噻吩与3-甲氧基-5-甲基三嗪异氰酸酯反应，制得噻磺隆。
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噻吩磺隆文献

Multiresidue method for the determination of 13 pesticides in three environmental matrices: water, sediments and fish muscle.

Talanta 85(3) , 1500-7, (2011)

Pesticides residues in aquatic ecosystems are an environmental concern which requires efficient analytical methods. In this study, we proposed a generic method for the quantification of 13 pesticides ...

Pesticide pressure and fish farming in barrage pond in Northeastern France. Part II: residues of 13 pesticides in water, sediments, edible fish and their relationships.

Environ. Sci. Pollut. Res. Int. 20(1) , 117-25, (2013)

Residues of pesticides in fish farming productions from barrage ponds are seldom studied in spite of increasing health questionings and environmental concerns. The purpose of this study is to establis...

The study of the interactions between heavy metals with sulfonylurea herbicides using ACE.

J. Chromatogr. Sci. 47(2) , 116-20, (2009)

The affinity capillary electrophoresis method was used in the study of interactions between heavy metals (Pb, Mn, La, Cd, and Ni) and the sulfonylurea herbicides (thifensulfuron, nicosulfuron and sulf...


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产品详情：丙酮中甲基噻吩磺隆标准溶液

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￥需询单/1g

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产品详情：Thifensulfuron-methyl

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价格：
￥514.9/100mg ￥4000.9/1g ￥2300.9/500mg ￥需询单/1g

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