杂醇油
杂醇油用途
1.主要用作溶剂,用于制药、植物提取、彩印、胶粘剂生产中,也用作染料、颜料稀释剂。
2.杂醇油直接使用不多,常用乙酸酯化作涂料用溶剂和醋酸纤维素类合成树脂的制造。其128~132℃馏分经乙酸酯化后可用作涂料、硝基喷漆、清漆、樟脑等的溶剂和香料、赛璐珞的制造原料。另外,与二硫化碳反应所得的异戊基黄原酸钾盐或钠盐,可作有色金属的浮选剂。
杂醇油名称
杂醇油物理化学性质
[ 密度 ]:
0.811~0.832
[ 沸点 ]:
bp 128-130°
[ 分子式 ]:
C5H12O
[ 分子量 ]:
88.148
[ 闪点 ]:
42°C
[ 精确质量 ]:
88.088814
[ LogP ]:
1.22
[ 蒸汽压 ]:
8.0±0.4 mmHg at 25°C
[ 折射率 ]:
n20/D1.400
杂醇油安全信息
[ 符号 ]:
GHS02, GHS05, GHS07
[ 信号词 ]:
Danger
[ 危害声明 ]:
H226-H302-H315-H318-H335 + H336
[ 警示性声明 ]:
P261-P280-P305 + P351 + P338
[ 风险声明 (欧洲) ]:
10-22-37/38-41-67
[ 安全声明 (欧洲) ]:
7/9-36/37/39-46
[ 危险品运输编码 ]:
1201
[ 包装等级 ]:
II
杂醇油制备
1.杂醇油是发酵法生产酒精的副产品。由白氨酸、异白氨酸等蛋白质分解物经酵母作用生成。其中含有异戊醇45%,异丁醇10%,旋光性戊醇5%,丙醇1.2%。此外尚含有乙醇、水及少量的丁醇、戊醇、己醇、庚醇和微量的醛、酸、酯、吡啶、生物碱等。粗制杂醇油经化学处理和精馏后,含异戊醇85%,旋光性戊醇15%。
精制方法 为除去其中的水分,可加入40%的食盐搅拌,静置一夜,盐析脱水后分馏。所得杂醇油收率为85%。若要得到纯度高的戊醇组分,可加入浓氢氧化钠溶液,使pH值达8.0~8.2,分出醇后再蒸馏,收集129~132℃的馏分。
杂醇油文献
J. Appl. Microbiol. 113(1) , 126-34, (2012)
For Ophiostoma (Ceratocystis) ulmi, the ability to undergo morphological change is a crucial factor for its virulence. To gain an understanding of quorum-sensing activity in O. ulmi as it relates to...
Selective dehydration of bio-ethanol to ethylene catalyzed by lanthanum-phosphorous-modified HZSM-5: influence of the fusel.Biotechnol. J. 5(11) , 1186-91, (2010)
Bio-ethanol dehydration to ethylene is an attractive alternative to oil-based ethylene. The influence of fusel, main byproducts in the fermentation process of bio-ethanol production, on the bio-ethano...
Fusel alcohols regulate translation initiation by inhibiting eIF2B to reduce ternary complex in a mechanism that may involve altering the integrity and dynamics of the eIF2B body.Mol. Biol. Cell 21 , 2202-16, (2010)
Recycling of eIF2-GDP to the GTP-bound form constitutes a core essential, regulated step in eukaryotic translation. This reaction is mediated by eIF2B, a heteropentameric factor with important links t...
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标题:杂醇油_用途_密度_沸点_杂醇油CAS号【8013-75-0】_化源网 地址:https://m.chemsrc.com/mip/cas/8013-75-0_1464478.html