全氟二苯甲酮

全氟二苯甲酮用途

Decafluorobenzophenone also known as perfluorobenzophenone. It was used in the synthesis of fluorinated acridones and acridines. Perfluorobenzophenone alcoholic solution generates ketyl and radical anion which can be studied by electron spin resonance spectra. Perfluorobenzophenone undergoes photolysis to form ketyl (C6F5)C.OH radica.

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全氟二苯甲酮名称

[ CAS 号 ]:
853-39-4

[ 中文名 ]:
全氟二苯甲酮

[ 英文名 ]:
Decafluorobenzophenone

[中文别名 ]:

[英文别名 ]:

EINECS 217-717-8
bis(2,3,4,5,6-pentafluorophenyl)methanone
MFCD00000295

全氟二苯甲酮物理化学性质

[ 密度 ]:
1.727 g/cm3

[ 沸点 ]:
206

[ 熔点 ]:
90-95 °C(lit.)

[ 分子式 ]:
C₁₃F₁₀O

[ 分子量 ]:
362.12300

[ 闪点 ]:
137.4ºC

[ 精确质量 ]:
361.97900

[ PSA ]:
17.07000

[ LogP ]:
4.30860

[ 外观性状 ]:
固体

[ 稳定性 ]:
Stable. Incompatible with strong oxidising agents.

全氟二苯甲酮MSDS

详细MSDS(安全技术说明书)

全氟二苯甲酮安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2914700090

全氟二苯甲酮合成路线

详细合成路线

全氟二苯甲酮上下游产品

全氟二苯甲酮上游产品

全氟二苯甲酮下游产品

全氟二苯甲酮海关

[ 海关编码 ]: 2914700090

[ 中文概述 ]:
2914700090 其他酮及醌的卤化、磺化衍生物（包括硝化和亚硝化衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

全氟二苯甲酮文献

The Electron Spin Resonance Spectra of the Photochemically Produced Perfluorobenzophenone Ketyl and Anion Radicals. Sargent FP and Bailey MG.

Can. J. Chem. 49(13) , 2350-2352, (1971)

The Photochemically Produced Ketyl of Perfluorobenzophenone: Electron Spin Resonance Studies of Solvent Effects. Sargent FP and Bailey MG.

Can. J. Chem. 51(19) , 3211-3216, (1973)

Orthogonal Synthesis of Fluorinated Acridones and Acridines from Perfluorobenzophenone. Del Buttero P, et al

European J. Org. Chem. 2011(12) , 2265-2271, (2011)

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