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[1,3-双(2,6-二异丙基苯基)咪唑-2-基亚基](3-氯吡啶基)二氯化钯(II)

名称

[ CAS 号 ]:
905459-27-0

[ 中文名 ]:
[1,3-双(2,6-二异丙基苯)咪唑-2-叉](3-氯吡啶)二氯化钯

[ 英文名 ]:
dichloro-[1,3-bis(diisopropylphenyl)imidazolylidene]-(3-chloropyridyl)palladium(ii)

[中文别名 ]:

PEPPSI-IPR 催化剂

[英文别名 ]:

物理化学性质

[ 熔点 ]:
240℃ (DEC.)

[ 分子式 ]:
C₃₂H₄₂Cl₃N₃Pd

[ 分子量 ]:
681.475

[ 精确质量 ]:
679.147888

[ PSA ]:
19.37000

[ LogP ]:
3.80850

[ 外观性状 ]:
固体;White to Light yellow powder to crystal

[ 储存条件 ]:
存放于惰性气体之中;避免空气

MSDS

详细MSDS(安全技术说明书)

安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H312-H332

[ 警示性声明 ]:
P280

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
20/21/22

[ 危险品运输编码 ]:
NONH for all modes of transport

[ 海关编码 ]:
28439000

文献

A user-friendly, all-purpose Pd-NHC (NHC=N-heterocyclic carbene) precatalyst for the negishi reaction: a step towards a universal cross-coupling catalyst.

Chemistry 12 , 4749, (2006)

We have developed the first user-friendly Negishi protocol capable of routinely cross-coupling all combinations of alkyl and aryl centers. The use of an easily synthesized, air stable, highly active, ...

Palladium complexes of N-heterocyclic carbenes as catalysts for cross-coupling reactions--a synthetic chemist's perspective.

Angew. Chem. Int. Ed. Engl. 46 , 2768, (2007)

Palladium-catalyzed C-C and C-N bond-forming reactions are among the most versatile and powerful synthetic methods. For the last 15 years, N-heterocyclic carbenes (NHCs) have enjoyed increasing popula...

Pd-catalyzed aryl amination mediated by well defined, N-heterocyclic carbene (NHC)-Pd precatalysts, PEPPSI.

Chemistry 14 , 2443, (2008)

Pd-N-heterocyclic carbene (NHC)-catalyzed Buchwald-Hartwig amination protocols mediated by Pd-PEPPSI precatalysts is described. These protocols provide access to a range of hindered and functionalized...

更多文献

[1,3-双(2,6-二异丙基苯基)咪唑-2-基亚基](3-氯吡啶基)二氯化钯(II)

名称

物理化学性质

MSDS

详细MSDS(安全技术说明书)

安全信息

文献

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