N,N-二甲基环己胺

N,N-二甲基环己胺用途

【用途一】
主要用作聚氨酯硬泡催化剂
【用途二】
N,N-二甲基环己胺可在范围广阔的硬性泡沫中使用。其中一项主要的应用是绝缘泡沫，包括喷雾剂，板块，胶层板及冷藏等用的配方。N，N-二甲基环己胺亦适用于硬性泡沫家俱框及装饰部件的制造。在硬泡制品中采用该催化剂，可作为主催化剂单独使用，无需加有机锡，也可根据工艺及制品要求辅以JD系列催化剂。该品也用作橡胶促进剂和合成纤维的中间体。
【用途三】
用作染料中间体，用于制香兰素、偶氮染料、三苯基甲烷染料，也可作溶剂、稳定剂、分析试剂等。也用作催化剂。

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N,N-二甲基环己胺名称

[ CAS 号 ]:
98-94-2

[ 中文名 ]:
N,N-二甲基环己胺

[ 英文名 ]:
N,N-Dimethylcyclohexanamine

[中文别名 ]:

[英文别名 ]:

Cyclohexanamine, N,N-dimethyl-
N,N-Dimethylcyclohexanamine
Dimethylaminocyclohexane
N,N-Dimethyl-1-cyclohexan-1-amine
N,N-Dimethylcyclohexylamine
MFCD00003844
EINECS 202-715-5

N,N-二甲基环己胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
162.0±8.0 °C at 760 mmHg

[ 熔点 ]:
-60 °C

[ 分子式 ]:
C₈H₁₇N

[ 分子量 ]:
127.227

[ 闪点 ]:
42.2±0.0 °C

[ 精确质量 ]:
127.136101

[ PSA ]:
3.24000

[ LogP ]:
2.12

[ 外观性状 ]:
透明液体

[ 蒸汽压 ]:
2.2±0.3 mmHg at 25°C

[ 折射率 ]:
1.460

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 水溶解性 ]:
10 g/L (20 ºC)

[ 凝固点 ]:
<-77℃

N,N-二甲基环己胺MSDS

详细MSDS(安全技术说明书)

N,N-二甲基环己胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GX1198000

CHEMICAL NAME :: Cyclohexylamine, N,N-dimethyl-

CAS REGISTRY NUMBER :: 98-94-2

BEILSTEIN REFERENCE NO. :: 1919922

LAST UPDATED :: 199710

DATA ITEMS CITED :: 12

MOLECULAR FORMULA :: C8-H17-N

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 348 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1889 mg/m3/2H

TOXIC EFFECTS :: Behavioral - muscle contraction or spasticity

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),54,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 370 mg/kg

TOXIC EFFECTS :: Behavioral - tremor Behavioral - ataxia Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536456

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 320 mg/kg

TOXIC EFFECTS :: Behavioral - muscle contraction or spasticity

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),54,1984

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1100 mg/m3/2H

TOXIC EFFECTS :: Behavioral - muscle contraction or spasticity

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 28(5),54,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 620 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 520 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete. (VEB Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem. Rep.) V.1- 1955- Volume(issue)/page/year: 20,393,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 1 mg/m3;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2994 No. of Facilities: 8 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 24 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2994 No. of Facilities: 563 (estimated) No. of Industries: 11 No. of Occupations: 16 No. of Employees: 6130 (estimated) No. of Female Employees: 253 (estimated)

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N,N-二甲基环己胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H311-H314-H330-H400

[ 警示性声明 ]:
P260-P273-P280-P284-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T:Toxic;

[ 风险声明 (欧洲) ]:
R10;R22;R23/24;R34

[ 安全声明 (欧洲) ]:
S26-S28-S36/37/39-S45-S61-S28A-S16

[ 危险品运输编码 ]:
UN 2264 8/PG 2

[ WGK德国 ]:
1

[ RTECS号 ]:
GX1198000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2921300090

N,N-二甲基环己胺合成路线

详细合成路线

N,N-二甲基环己胺上下游产品

N,N-二甲基环己胺上游产品

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N,N-二甲基环己胺制备

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N,N-二甲基环己胺海关

[ 海关编码 ]: 2921300090

[ 中文概述 ]:
2921300090 其他环（烷，烯，萜烯）单胺或多胺（包括其衍生物及它们的盐）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

N,N-二甲基环己胺文献

Liquid membrane work-up of blood plasma samples applied to gas chromatographic determination of aliphatic amines.

J. Chromatogr. A. 573(2) , 191-200, (1992)

A technique for sample work-up and enrichment using a supported liquid membrane in an automated flow system, connected to a gas chromatograph, was used for the determination of aliphatic amines in hum...

Switchable hydrophilicity solvents for lipid extraction from microalgae for biofuel production

Bioresour. Technol. 118 , 628-32, (2012)

Highlights ► We extracted lipids from microalgae using switchable hydrophilicity solvents (SHS). ► SHS extractions at room temperature yielded more intact triacylglycerols than at 80°C. ► Extractions ...

Lewis base-catalyzed three-component Strecker reaction on water. An efficient manifold for the direct alpha-cyanoamination of ketones and aldehydes.

Chem. Commun. (Camb.) (44) , 6839-41, (2009)

The first three-component organocatalyzed Strecker reaction operating on water has been developed. The manifold utilizes ketones (aldehydes) as the starting carbonyl component, aniline as the primary ...

更多文献

N,N-二甲基环己胺

N,N-二甲基环己胺用途

N,N-二甲基环己胺名称

N,N-二甲基环己胺物理化学性质

N,N-二甲基环己胺MSDS

详细MSDS(安全技术说明书)

N,N-二甲基环己胺毒性和生态

CHEMICAL IDENTIFICATION

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

N,N-二甲基环己胺安全信息

N,N-二甲基环己胺合成路线

详细合成路线

N,N-二甲基环己胺上下游产品

N,N-二甲基环己胺上游产品

N,N-二甲基环己胺下游产品

N,N-二甲基环己胺制备

N,N-二甲基环己胺海关

N,N-二甲基环己胺文献

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