Organic reactions of reduced species of sulfur dioxide

…, MD Hoey, AL Finocchio, DC Dittmer

文献索引：Jarvis, William F.; Hoey, Michael D.; Finocchio, Alfred L.; Dittmer, Donald C. Journal of Organic Chemistry, 1988 , vol. 53, # 24 p. 5750 - 5756

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被引用次数: 48

摘要

Rongalite (sodium hydroxymethanesulfinate or sodium formaldehydesulfoxylate) reacts with organic halides in a variety of ways depending on the structure of the organic compound. Benzyl and other alkyl halides give sulfones in generally good yields; but in several cases, reduction (2, 4-dinitrobenzyl bromide, phenacyl halides) or coupling@-nitrobenzyl bromide under basic conditions, phenacyl bromide or iodide) of the halide occurs. Addition of ...