Arylsulfonoxylation of aromatic compounds. II. Partial rate factors for the nitrophenylsulfonoxylation of alkylbenzenes

RL Dannley, JE Gagen, OJ Stewart

文献索引：Dannley,R.L. et al. Journal of Organic Chemistry, 1970 , vol. 35, # 9 p. 3076 - 3079

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被引用次数: 29

摘要

Ethyl acetate is resistant to attack by nitrobenzenesulfonyl peroxides and is a suitable solvent for sulfonoxylations. In the thermal decomposition of o-and m-nitrobenzenesulfonyl peroxides in alkylbenzenes there are no products resulting from a side-chain hydrogen abstraction characteristic of a homolytic reaction. Competitive 0-and m- nitrophenylsulfonoxylations gave, respectively, for le. &^: benzene, 1.0; toluene, 13.3, 19.0 ...