Easily accessible chiral amino-phosphinite ligands for highly enantioselective palladium-mediated allylic alkylation

…, H Zhang, L Gong, A Mi, X Cui, Y Jiang, MCK Choi…

文献索引：Chen, Guoshu; Li, Xin; Zhang, Haile; Gong, Liuzhu; Mi, Aiqiao; Cui, Xin; Jiang, Yaozhong; Choi, Michael C.K.; Chan, Albert S.C. Tetrahedron Asymmetry, 2002 , vol. 13, # 8 p. 809 - 813

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被引用次数: 23

摘要

Palladium-catalyzed asymmetric allylic alkylation of 1, 3-diphenyl-2-propenyl acetate with the dimethyl malonate–BSA–LiOAc system has been successfully carried out in the presence of easily prepared new chiral amino-phosphinite ligands such as 3b and 3c to result in good yields and excellent enantioselectivities of up to 95% ee