Syntheses and reactions of fluorine-containing aromatic ketones.

H Kimoto, H Muramatsu, K Inukai

文献索引：Kimoto,H. et al. Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 1642 - 1649

全文：HTML全文

被引用次数: 9

摘要

Phenyl 1, 1, 2, 3, 3, 3-hexafluoropropyl ketone (I) and 2, 2, 3-trifluoro-3-(trifluoromethyl) indanone (II) were synthesized by the radical-addition reaction of benzaldehyde to hexafluoropropene. The reduction with NaBH 4 and the Grignard reaction with methylmagnesium iodide of these ketones gave the corresponding secondary and tertiary alcohols respectively. A Clemmensen reduction, alkaline hydrolyses, and reactions with ...