Die Hydrolyse von 6exo??substituierten 2exo??und 2endo??Norbornylestern der p??Toluolsulfonsäure. Norbornanreihe. 3. Mitteilung

…, CA Grob, G Von Sprecher, A Waldner

文献索引：Fischer, Walter; Grob, Cyril A.; Sprecher, Georg von; Waldner, Adrian Helvetica Chimica Acta, 1980 , vol. 63, # 4 p. 928 - 937

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被引用次数: 13

摘要

Summary Hydrolysis of the 6exo-substituted 2exo-and 2endo-norbornyl p-toluenesulfonates lb-1 and 2b-1, respectively, in 70% dioxane led to different amounts of the following products: Unrearranged 2exo-norbornanols 3 and norbornenes 5, accompanied in somes cases by small amounts of the rearranged Rendo-epimers 4 and 6 and by nortricyclenes 7. When the 6exo-substituent was a nucleophilic group as in le-l and 2e-1, various amounts ...