Reactions of triethylgermyllithium with N, N-dialkylated carboxamides

DA Bravo-Zhivotovskii, SD Pigarev…

文献索引：Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Kalikhman, I. D.; Vyazankina, O. A.; Vyazankin, N. S. Journal of Organometallic Chemistry, 1983 , vol. 248, # 1 p. 51 - 60

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被引用次数: 20

摘要

Abstract The reactions of triethylgermyllithium with N, N-dialkylated carboxamides have been investigated. N, N-Dimethylacetamide, N, N-dimethylpivalamide, N, N- diethyltrifluoroacetamide and N, N-diethylbenzamide act on triethylgermyllithium, which is made from bis (triethylgermyl) mercury and lithium in hexane, to release the corresponding acyltriethylgermanes as the principal product. The regioselectivity of the present reactions ...